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研究水热预处理棕榈空果串燃烧过程中的结垢沉积:工业水热反应器的中试研究。

Investigating fouling deposition during combustion of hydrothermally treated palm empty fruit Bunch: Pilot-Scale study for industrial hydrothermal reactor.

机构信息

The Joint Graduate School of Energy and Environment, King Mongkut's University of Technology Thonburi, Bangkok, Thailand; Center of Excellence on Energy Technology and Environment, Ministry of Higher-Education, Science, Research and Innovation, Thailand.

The Joint Graduate School of Energy and Environment, King Mongkut's University of Technology Thonburi, Bangkok, Thailand; Center of Excellence on Energy Technology and Environment, Ministry of Higher-Education, Science, Research and Innovation, Thailand.

出版信息

Bioresour Technol. 2024 Aug;406:130969. doi: 10.1016/j.biortech.2024.130969. Epub 2024 Jun 13.

Abstract

Inorganic elements in palm empty fruit bunch (EFB) are problematic in boiler operation, causing slagging and fouling deposits. The first pilot-scale hydrothermal treatment (HTT) system was commenced in a palm oil mill to remove undesirable elements. Fuel properties, combustion behavior, and fouling deposition of HTT-EFB were investigated. Liquid temperatures and treatment times in the HTT system significantly altered EFB-fuel properties. At ≥ 60 °C, potassium removals of at least 78 % were achieved, generating EFB-fuel containing potassium below 0.5 %wt. Later, a series of EFB combustion experiments were conducted in a specially designed fixed-bed reactor to simulate the tube surface of industrial boilers. Fouling deposition from HTT-EFB combustion reduced to below half of untreated EFB at all HTT conditions and combustion temperatures studied. The deposit-to-fuel ratio of HTT-EFB combusted at 1,000 °C was 37.3 % lower than untreated EFB combusted at a typical EFB boiler at 800 °C. Results demonstrated great potential for HTT-EFB in industrial applications.

摘要

棕榈空果串(EFB)中的无机元素在锅炉运行中存在问题,会导致结渣和积垢。首个棕榈油厂中试规模的水热处理(HTT)系统开始运行,以去除不良元素。研究了 HTT-EFB 的燃料特性、燃烧行为和积垢沉积。HTT 系统中的液体温度和处理时间显著改变了 EFB-燃料的特性。在≥60°C时,钾的去除率至少达到 78%,生成的 EFB-燃料中钾含量低于 0.5%wt。随后,在专门设计的固定床反应器中进行了一系列 EFB 燃烧实验,以模拟工业锅炉的管表面。在所有 HTT 条件和研究的燃烧温度下,HTT-EFB 燃烧产生的积垢沉积减少到未处理 EFB 的一半以下。在 1000°C 下燃烧的 HTT-EFB 的沉积-燃料比比在典型的 800°C EFB 锅炉中燃烧的未处理 EFB 低 37.3%。结果表明,HTT-EFB 在工业应用中有很大的潜力。

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