Highly conductive, rapid self-healing, and anti-freezing poly(3,4-ethylenedioxythiophene)/lignosulfonate-cationic guar gum ionogels for multifunctional sensors.

Soft ionic conductors exhibit immense potential for applications in soft ionotronics, including ionic skin, human-machine interface, and soft luminescent device. Nevertheless, the majority of ionogel-based soft ionic conductors are plagued by issues such as freezing, evaporation, liquid leakage, and inadequate self-healing capabilities, thereby constraining their usability in complex environments. In this study, we present a novel strategy for fabricating conductive ionogels through the proportionally mixing cationic guar gum (CGG), water, 1-butyl-3-methylimidazolium chloride (BmimCl)/glycerol eutectic-based ionic liquid, and poly(3,4-ethylenedioxythiophene)/lignosulfonate (PEDOT/LS). The resultant benefits from strong hydrogen bonding and electrostatic interactions among its constituents, endowing it with an ultrafast self-healing capability (merely 30 s) while sustaining high electrical conductivity (~16.5 mS cm). Moreover, it demonstrates exceptional water retention (62 % over 10 days), wide temperature tolerance (-20 to 60 °C), and injectability. A wearable sensor fabricated from this ionogel displayed remarkable sensitivity (gauge factor = 17.75) and a rapid response to variations in strain, pressure, and temperature, coupled with both long-term stability and wide working temperature range. These attributes underscore its potential for applications in healthcare devices and flexible electronics.