Zhang Yuxuan, Yan Shi, Wang Xin, Guan Yue, Du Changmei, Fan Tiancong, Li Hanhua, Zhai Junjun
Department of Engineering Mechanics, Harbin University of Science and Technology, Harbin 150000, China.
Aulin College, Northeast Forestry University, Harbin 150000, China.
Polymers (Basel). 2024 May 23;16(11):1477. doi: 10.3390/polym16111477.
Resin matrix composites (RCs) have better thermal and chemical stability, so they are widely used in engineering fields. In this study, the aging process and mechanism of two different types of resin-based three-dimensional four-way braided composites (H15 and S15) under different hygrothermal aging conditions were studied. The effect of aging behavior on the mechanical properties of RCs was also studied. Three different aging conditions were studied: Case I, 40 °C Soak; Case II, 70 °C Soak; and Case III, 70 °C-85% relative humidity (RH). It was found that the hygroscopic behavior of RCs in the process of moisture-heat aging conforms to Fick's second law. Higher temperatures and humidity lead to higher water absorption. The equilibrium hygroscopic content of H15 was 1.46% (Case II), and that of S15 was 2.51% (Case II). FT-IR revealed the different hygroscopic mechanisms of H15 and S15 in terms of aging behavior. On the whole, the infiltration behavior of water molecules is mainly exhibited in the process of wet and thermal aging. At the same time, the effect of the aging process on resin matrices was observed using SEM. It was found that the aging process led to the formation of microchannels on the substrate surface of S15, and the formation of these channels was the main reason for the better moisture absorption and lower mechanical strength of S15. At the same time, this study further found that temperature and oxygen content are the core influences on post-aging strength. The LVI experiment also showed that the structural changes and deterioration effects occurring after aging reduced the strength of the studied material.
树脂基复合材料(RCs)具有更好的热稳定性和化学稳定性,因此在工程领域得到广泛应用。本研究对两种不同类型的树脂基三维四向编织复合材料(H15和S15)在不同湿热老化条件下的老化过程及机理进行了研究。同时,研究了老化行为对RCs力学性能的影响。研究了三种不同的老化条件:情况I,40°C浸泡;情况II,70°C浸泡;以及情况III,70°C - 85%相对湿度(RH)。研究发现,RCs在湿热老化过程中的吸湿行为符合菲克第二定律。温度和湿度越高,吸水率越高。H15在情况II下的平衡吸湿量为1.46%,S15在情况II下的平衡吸湿量为2.51%。傅里叶变换红外光谱(FT - IR)揭示了H15和S15在老化行为方面不同的吸湿机理。总体而言,水分子的渗透行为主要表现在湿热老化过程中。同时,通过扫描电子显微镜(SEM)观察了老化过程对树脂基体的影响。研究发现,老化过程导致S15基体表面形成微通道,这些通道的形成是S15吸湿性能较好且机械强度较低的主要原因。同时,本研究进一步发现温度和氧含量是影响老化后强度的核心因素。激光超声成像(LVI)实验还表明,老化后发生的结构变化和劣化效应降低了所研究材料的强度。