Liu Xiaodong, Su Qingyong, Zhu Jing, Song Xiaopeng
School of Energy and Built Environment, Guilin University of Aerospace Technology, Guilin 541004, China.
College of Civil Engineering and Architecture, Harbin University of Science and Technology, Harbin 150080, China.
Polymers (Basel). 2023 May 28;15(11):2490. doi: 10.3390/polym15112490.
Carbon fiber-reinforced polymer (CFRP) composites have been widely used in civil engineering structures due to their excellent mechanical and durability properties. The harsh service environment of civil engineering leads to significant degradation of the thermal and mechanical performances of CFRP, which then reduces its service reliability, service safety, and life. Research on the durability of CFRP is urgently needed to understand the long-term performance degradation mechanism. In the present study, the hygrothermal aging behavior of CFRP rods was investigated experimentally through immersion in distilled water for 360 days. The water absorption and diffusion behavior, the evolution rules of short beam shear strength (SBSS), and dynamic thermal mechanical properties were obtained to investigate the hygrothermal resistance of CFRP rods. The research results show that the water absorption behavior conforms to Fick's model. The ingression of water molecules leads to a significant decrease in SBSS and glass transition temperature (Tg). This is attributed to the plasticization effect of the resin matrix and interfacial debonding. Furthermore, the Arrhenius equation was used to predict the long-term life of SBSS in the actual service environment based on the time-temperature equivalence theory, obtaining a stable strength retention of SBSS of 72.78%, which was meaningful to provide a design guideline for the long-term durability of CFRP rods.
碳纤维增强聚合物(CFRP)复合材料因其优异的力学性能和耐久性,已在土木工程结构中得到广泛应用。土木工程恶劣的服役环境会导致CFRP的热性能和力学性能显著退化,进而降低其服役可靠性、服役安全性和使用寿命。迫切需要开展CFRP耐久性研究,以了解其长期性能退化机制。在本研究中,通过将CFRP棒材浸泡在蒸馏水中360天,对其湿热老化行为进行了实验研究。获得了吸水与扩散行为、短梁剪切强度(SBSS)的演变规律以及动态热机械性能,以研究CFRP棒材的抗湿热性能。研究结果表明,吸水行为符合菲克模型。水分子的侵入导致SBSS和玻璃化转变温度(Tg)显著降低。这归因于树脂基体的增塑作用和界面脱粘。此外,基于时间-温度等效理论,利用阿伦尼乌斯方程预测了SBSS在实际服役环境中的长期寿命,得到SBSS稳定的强度保持率为72.78%,这对于为CFRP棒材的长期耐久性提供设计指导具有重要意义。