Akter Mahmuda, Ozdemir Huseyin, Bilisik Kadir
Nano/Microfiber Preform Design and Composite Laboratory, Department of Textile Engineering, Faculty of Engineering, Erciyes University, Talas, Kayseri 38039, Turkey.
Department of Apparel Engineering, Faculty of Fashion Design and Apparel Engineering, Bangladesh University of Textiles, Tejgaon, Dhaka 1208, Bangladesh.
Polymers (Basel). 2024 May 23;16(11):1483. doi: 10.3390/polym16111483.
This paper presents an experimental investigation of nanocomposites composed of three ratios of epoxy/graphene nanoplatelets (GNPs) by weight. The 0.1, 0.2, and 0.3 wt.% specimens were carefully manufactured, and their mechanical and thermal conductivity properties were examined. The tensile strength and modulus of epoxy/GNPs were enhanced by the large surface area of graphene nanoplatelets, causing crack deflection that created new fracture fronts and friction because of the rough fracture surface. However, the compressive strength was gradually reduced as GNP loading percentages increased. This was probably due to severe plastic yielding on the epoxy, leading to catastrophic axial splitting caused by premature fractures. Furthermore, the highest thermal conductivity was 0.1283 W/m-K, representing a 20.92% improvement over neat epoxy (0.1061 W/m-K) when 0.3 wt.% GNPs were added to the epoxy. This was because of efficient heat propagation in the GNPs due to electron movement through percolative paths. The tensile failure mode in epoxy/GNP nanocomposites showed a few deflected and bifurcated rough cracks and brittle, dimple-like fractures. Contrarily, compressive failure mode in GNP-added epoxy showed plastic flexural buckling and brittle large-axial splitting. The epoxy/GNP nanocomposites were considered a damage-tolerant material.
本文介绍了对三种重量比的环氧/石墨烯纳米片(GNP)组成的纳米复合材料进行的实验研究。精心制备了0.1、0.2和0.3 wt.%的试样,并对其力学性能和热导率进行了检测。环氧/GNP的拉伸强度和模量因石墨烯纳米片的大表面积而提高,这导致裂纹偏转,产生了新的断裂前沿,并因粗糙的断裂表面而产生摩擦。然而,随着GNP负载百分比的增加,抗压强度逐渐降低。这可能是由于环氧树脂上严重的塑性屈服,导致过早断裂引起灾难性的轴向分裂。此外,最高热导率为0.1283 W/m-K,当向环氧树脂中添加0.3 wt.%的GNP时,相较于纯环氧树脂(0.1061 W/m-K)提高了20.92%。这是由于电子通过渗透路径移动,使得GNP中热量有效传播。环氧/GNP纳米复合材料的拉伸破坏模式表现为一些偏转和分叉的粗糙裂纹以及脆性的、酒窝状断裂。相反,添加GNP的环氧树脂的压缩破坏模式表现为塑性弯曲屈曲和脆性的大轴向分裂。环氧/GNP纳米复合材料被认为是一种损伤容限材料。