Głowniak Sylwia, Szczęśniak Barbara, Choma Jerzy, Jaroniec Mietek
Institute of Chemistry, Military University of Technology, 00-908 Warsaw, Poland.
Department of Chemistry and Biochemistry & Advanced Materials and Liquid Crystal Institute, Kent State University, Kent, OH 44242, USA.
Molecules. 2024 Jun 6;29(11):2698. doi: 10.3390/molecules29112698.
Metal-organic structures have great potential for practical applications in many areas. However, their widespread use is often hindered by time-consuming and expensive synthesis procedures that often involve hazardous solvents and, therefore, generate wastes that need to be remediated and/or recycled. The development of cleaner, safer, and more sustainable synthesis methods is extremely important and is needed in the context of green chemistry. In this work, a facile mechanochemical method involving water-assisted ball milling was used for the synthesis of MOF-303. The obtained MOF-303 exhibited a high specific surface area of 1180 m/g and showed an excellent CO adsorption capacity of 9.5 mmol/g at 0 °C and under 1 bar.
金属有机结构在许多领域具有巨大的实际应用潜力。然而，它们的广泛应用常常受到耗时且昂贵的合成程序的阻碍，这些程序通常涉及危险溶剂，因此会产生需要修复和/或回收的废物。开发更清洁、更安全、更可持续的合成方法极为重要，这在绿色化学背景下是必要的。在这项工作中，一种涉及水辅助球磨的简便机械化学方法被用于合成MOF-303。所获得的MOF-303表现出1180 m/g的高比表面积，并且在0°C和1巴压力下显示出9.5 mmol/g的优异CO吸附容量。
