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沸石粉改性再生混凝土冻融循环耐久性及机理分析

Freeze-Thaw Cycle Durability and Mechanism Analysis of Zeolite Powder-Modified Recycled Concrete.

作者信息

Yu Teng, Zhang Yimeng, Cao Liang, Cao Peng, Zhou Changjun, Gu Shenglong

机构信息

School of Civil Engineering and Water Resources, Qinghai University, Xining 810016, China.

Laboratory of Ecological Protection and High Quality Development in the Upper Yellow River, Xining 810016, China.

出版信息

Materials (Basel). 2024 Jun 1;17(11):2671. doi: 10.3390/ma17112671.

Abstract

The inferior mechanical performance and freeze-thaw (FT) resistance of recycled concrete are mostly due to the significant water absorption and porosity of recycled coarse particles. In this study, different dosages of zeolite powder were used in recycled concrete. A series of macroscopic tests were used to evaluate the workability and FT durability of zeolite powder-modified recycled concrete (ZPRC). X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to reveal the micro-mechanisms of FT resistance in ZPRC. The results show that the increase in zeolite powder content leads to a decrease in the slump and water absorption of ZPRC. Additionally, ZPRC with 10% zeolite powder has superior mechanical characteristics and tolerance to FT conditions. The higher strength and FT resistance of the ZPRC can be attributed to the particle-filling effect, water storage function, and pozzolanic reaction of zeolite powder, which results in a denser microstructure. The particle-filling effect of zeolite powder promotes the reduction of surface pores in recycled coarse aggregates (RCAs). The water storage function of zeolite powder can provide water for the secondary hydration of cement particles while reducing the free water content in ZPRC. The pozzolanic reaction of zeolite powder can also promote the generation of hydrated calcium silicate and anorthite, thereby making the microstructure of ZPRC more compact. These results provide theoretical guidance for the engineering application of recycled concrete in cold regions.

摘要

再生混凝土较差的力学性能和抗冻融性能主要归因于再生粗颗粒显著的吸水性和孔隙率。在本研究中,再生混凝土中使用了不同剂量的沸石粉。采用一系列宏观试验来评估沸石粉改性再生混凝土(ZPRC)的工作性和冻融耐久性。利用X射线衍射(XRD)和扫描电子显微镜(SEM)揭示ZPRC中抗冻融的微观机制。结果表明,沸石粉含量的增加导致ZPRC的坍落度和吸水率降低。此外,含10%沸石粉的ZPRC具有优异的力学性能和耐冻融性能。ZPRC较高的强度和抗冻融性可归因于沸石粉的颗粒填充效应、储水功能和火山灰反应,这导致了更致密的微观结构。沸石粉的颗粒填充效应促进了再生粗骨料(RCA)表面孔隙的减少。沸石粉的储水功能可以为水泥颗粒的二次水化提供水分,同时降低ZPRC中的自由水含量。沸石粉的火山灰反应还可以促进水化硅酸钙和钙长石的生成,从而使ZPRC的微观结构更加致密。这些结果为再生混凝土在寒冷地区的工程应用提供了理论指导。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0257/11173878/2fe2952b7450/materials-17-02671-g001.jpg

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