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铼含量对钨铼合金中氦脱附行为的影响

The Influence of Rhenium Content on Helium Desorption Behavior in Tungsten-Rhenium Alloy.

作者信息

Liu Yongli, Song Yamin, Dong Ye, Zhu Te, Zhang Peng, Wu Lu, Cao Xingzhong, Wang Baoyi

机构信息

The First Sub-Institute, Nuclear Power Institute of China, Chengdu 610005, China.

Multi-Disciplinary Research Division, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.

出版信息

Materials (Basel). 2024 Jun 4;17(11):2732. doi: 10.3390/ma17112732.

Abstract

To investigate the influence of different rhenium contents on the helium desorption behavior in tungsten-rhenium alloys, pure tungsten and tungsten-rhenium alloys were irradiated with helium under the same conditions. All irradiated samples were characterized using TDS and DBS techniques. The results indicate that the addition of rhenium can reduce the total helium desorption quantity in tungsten-rhenium alloys and slightly accelerate the reduction in the concentration of vacancy-type defects accompanying helium dissociation. The desorption activation energy of helium is approximately 2 eV at the low-temperature peak (785 K) and about 4 eV at the high-temperature peak (1475 K). An increase in rhenium content causes the desorption peak to shift towards higher temperatures (>1473 K), which is attributed to the formation of the stable complex structures between rhenium and vacancies. Besides, the migration of He-vacancy complexes towards traps and dynamic annealing processes both lead to the recovery of vacancy-type defects, resulting in a decrease in the positron annihilation parameters.

摘要

为了研究不同铼含量对钨铼合金中氦脱附行为的影响,在相同条件下用氦对纯钨和钨铼合金进行辐照。所有辐照样品均采用热脱附谱(TDS)和深能级瞬态谱(DBS)技术进行表征。结果表明,铼的加入可降低钨铼合金中的总氦脱附量,并略微加速伴随氦解离的空位型缺陷浓度的降低。在低温峰(785 K)处氦的脱附活化能约为2 eV,在高温峰(1475 K)处约为4 eV。铼含量的增加导致脱附峰向更高温度(>1473 K)移动,这归因于铼与空位之间形成了稳定的复合结构。此外,氦-空位复合体向陷阱的迁移和动态退火过程均导致空位型缺陷的恢复,从而导致正电子湮没参数降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1c2c/11173476/46d7702311f1/materials-17-02732-g001a.jpg

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