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铽的活性和核衰变数据的测定。

Determination of the activity and nuclear decay data of Tb.

作者信息

Riffaud Jonathan, Kossert Karsten, Takács Marcell Péter, Chiera Nadine M, Schumann Dorothea, Studer Dominik, Röttger Stefan, Wendt Klaus

机构信息

Physikalisch-Technische Bundesanstalt (PTB), Bundesallee 100, 38116, Braunschweig, Germany.

Physikalisch-Technische Bundesanstalt (PTB), Bundesallee 100, 38116, Braunschweig, Germany.

出版信息

Appl Radiat Isot. 2024 Sep;211:111407. doi: 10.1016/j.apradiso.2024.111407. Epub 2024 Jun 15.

DOI:10.1016/j.apradiso.2024.111407
PMID:38897113
Abstract

Terbium-157 was radiochemically extracted from an irradiated tantalum target. Since the resulting material contained a significant impurity of Tb, Tb was isotopically purified using laser resonance ionization at the RISIKO mass separator in Mainz and then implanted on an aluminum (Al) foil. The implanted Tb was measured by two different calibrated gamma-ray spectrometers to determine photon emission rates. After dissolving the Al foil, a high purity Tb solution was obtained. The corresponding activity concentration was determined with a low relative uncertainty of 0.52% through a combination of liquid scintillation counting using the TDCR method and 4π(X,e)(LS)-(X,γ)(CeBr) coincidence counting. By combining the results from all measurement techniques, emission intensities for K X-rays and gamma-rays were derived and found to be 16.05(31)% and 0.0064(2)%, respectively. The probability for K electron capture of the first forbidden non-unique transition to the ground state was determined to be 17.16(35)%. The probabilities for the electron-capture branch to the excited level and the ground state were found to be 0.084(4)% and 99.916(4)%, respectively. A Q value of 60.23(18) keV was estimated based on simplified BetaShape calculations, assuming an allowed transition.

摘要

从辐照钽靶中放射化学提取铽-157。由于所得材料含有大量铽杂质,在美因茨的RISIKO质量分离器中使用激光共振电离对铽进行同位素纯化,然后将其植入铝箔上。通过两种不同校准的伽马射线光谱仪测量植入的铽,以确定光子发射率。溶解铝箔后,得到高纯度铽溶液。通过使用TDCR方法的液体闪烁计数和4π(X,e)(LS)-(X,γ)(CeBr)符合计数相结合,以0.52%的低相对不确定度确定了相应的活度浓度。结合所有测量技术的结果,得出K X射线和伽马射线的发射强度分别为16.05(31)%和0.0064(2)%。确定到基态的首次禁戒非唯一跃迁的K电子俘获概率为17.16(35)%。发现到激发态和基态的电子俘获分支概率分别为0.084(4)%和99.916(4)%。基于简化的BetaShape计算,假设为允许跃迁,估计出Q值为60.23(18)keV。

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