Combining Local Range Separation and Local Hybrids: A Step in the Quest for Obtaining Good Energies and Eigenvalues from One Functional.

Some of the most successful exchange-correlation approximations in density functional theory are "hybrids", i.e., they rely on combining semilocal density functionals with exact nonlocal Fock exchange. In recent years, two classes of hybrid functionals have emerged as particularly promising: range-separated hybrids on the one hand, and local hybrids on the other hand. These functionals offer the hope to overcome a long-standing "observable dilemma", i.e., the fact that density functionals typically yield either a good description of binding energies, as obtained, e.g., in global and local hybrids, or physically interpretable eigenvalues, as obtained, e.g., in optimally tuned range-separated hybrids. Obtaining both of these characteristics from one and the same functional with the same set of parameters has been a long-standing challenge. We here discuss combining the concepts of local range separation and local hybrids as part of a constraint-guided quest for functionals that overcome the observable dilemma.