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棕榈酸乙酯对丙二醇 - 乙醇溶液中香气化合物释放的影响及其机制。

Effects of ethyl palmitate on the release of aroma compounds in propanediol-ethanol solution and its mechanisms.

作者信息

Guo Wei-Wei, Luo Li-Wen, Wang Ding-Zhong, Fu Ying-Jie, Xi Hui, Sun Shi-Hao

机构信息

Flavour Science Research Center, College of Chemistry, Zhengzhou University, Zhengzhou, China.

Department of Flavor, Zhengzhou Tobacco Research Institute, Zhengzhou, China.

出版信息

Front Chem. 2024 Jun 10;12:1381835. doi: 10.3389/fchem.2024.1381835. eCollection 2024.

Abstract

Long-chain esters (LCEs) are known to affect aroma perception, but the mechanism of their effects remains unclear. In this study, ethyl palmitate (EP), an important LCE in flower absolute (OFFA), was selected as a target to identify its role and mechanism. The release characteristics of 10 aroma compounds from OFFA with and without EP were obtained by headspace gas chromatography mass spectrometry (HS-GC/MS) and olfactometry evaluation, respectively. The results show that EP changes the release behaviors of volatile compounds in solution, increases their olfactory detection thresholds (ODTs), and reduces the equilibrium headspace concentrations. According to Whitman's two-film model, EP was found to change the partition coefficients and mass transfer coefficients of the compounds between the liquid and gas phases. This indicates that EP plays an important role in the scent formation of a flavor product and that it is very valuable for the style design of the flavor product.

摘要

长链酯(LCEs)已知会影响香气感知,但其作用机制仍不清楚。在本研究中,棕榈酸乙酯(EP)作为花净油(OFFA)中的一种重要长链酯,被选作目标来确定其作用和机制。分别通过顶空气相色谱 - 质谱联用(HS - GC/MS)和嗅觉测定评估,获得了含和不含EP的OFFA中10种香气化合物的释放特性。结果表明,EP改变了挥发性化合物在溶液中的释放行为,提高了它们的嗅觉检测阈值(ODTs),并降低了平衡顶空浓度。根据惠特曼双膜模型,发现EP改变了化合物在液相和气相之间的分配系数和传质系数。这表明EP在风味产品的香气形成中起重要作用,并且对风味产品的风格设计非常有价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f44/11194716/da28405ef77c/fchem-12-1381835-g001.jpg

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