Xing Chengwei, Zhu Bohan, Chiang Kingsley C K, Chen Cheng, Liu Lingxiao, Chang Zhibin
Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang'an University, South 2nd Ring Road Middle Section, Xi'an 710064, China.
School of Highway, Chang'an University, South 2nd Ring Road Middle Section, Xi'an 710064, China.
Polymers (Basel). 2024 Jun 14;16(12):1709. doi: 10.3390/polym16121709.
The aim of this paper is to investigate the aging mechanism of asphalt in the sea salt erosion environment from a rheological point of view. In order to simulate the real pavement aging process in the sea salt erosion environment, base asphalt and Styrene-Butadiene-Styrene (SBS)-modified asphalt were selected for salt environment aging tests. The asphalt samples were aged via a thin film oven test (TFOT) and a pressure aging vessel (PAV) test. Then, thermo-oxidizing conditions were created after the samples were immersed in salt solution, mixed with four different concentrations of sodium chloride (NaCl) and sodium sulphate (NaSO), to investigate the aging state of asphalt. Temperature scan (TS), frequency scan (FS), and multiple stress creep and recovery (MSCR) tests performed using a Dynamic Shear Rheometer (DSR) were used to investigate the effects on the rheological properties of aged asphalt in a salt environment. The results showed that both base asphalt and SBS-modified asphalt were aged to different degrees under mixed salt solutions. The two asphalt samples aged in a salt environment showed increased hardness. SBS-modified asphalt exhibited higher aging resistance compared with base asphalt in the sea salt environment. However, due to the degradation of the SBS modifier and the aging of base asphalt, the properties of the SBS-modified asphalt showed more obvious complexity with changes in salt solution concentrations.
本文旨在从流变学角度研究海盐侵蚀环境中沥青的老化机理。为模拟海盐侵蚀环境下真实的路面老化过程,选用基质沥青和苯乙烯-丁二烯-苯乙烯(SBS)改性沥青进行盐环境老化试验。沥青样品通过薄膜烘箱试验(TFOT)和压力老化容器(PAV)试验进行老化。然后,将样品浸入盐溶液中,与四种不同浓度的氯化钠(NaCl)和硫酸钠(Na₂SO₄)混合,创造热氧化条件,以研究沥青的老化状态。使用动态剪切流变仪(DSR)进行温度扫描(TS)、频率扫描(FS)和多重应力蠕变恢复(MSCR)试验,以研究盐环境中老化沥青的流变性能受到的影响。结果表明,在混合盐溶液作用下,基质沥青和SBS改性沥青均发生了不同程度的老化。在盐环境中老化的两种沥青样品硬度增加。在海盐环境中,SBS改性沥青比基质沥青表现出更高的抗老化性能。然而,由于SBS改性剂的降解和基质沥青的老化,SBS改性沥青的性能随盐溶液浓度的变化表现出更明显的复杂性。