Purge and trap method for determination of ethylene dibromide in table-ready foods.

An improved method has been developed for the determination of ethylene dibromide (EDB, 1,2-dibromoethane) in a variety of table-ready foods. Samples are mixed with water and sparged with nitrogen for 1 h with stirring in a water bath at 100 degrees C. The EDB collected on the adsorbent Tenax TA is eluted with hexane and determined by gas chromatography (GC) with electron capture (EC) and confirmed with Hall electrolytic conductivity (HECD) detection using a second GC column. The highest levels of EDB were also confirmed by full scan GC/mass spectrometry (GC/MS). Twenty-five table-ready foods from the Food and Drug Administration's Total Diet Study that were analyzed by this method exhibited levels up to 70 ppb (pecans). Recoveries from fortified samples ranged from 91 to 104%. Values from this procedure were compared to those obtained by a modified Rains and Holder codistillation method. In all 25 samples this purge and trap procedure showed equivalent or superior recoveries and detected levels of EDB.