Correa Stephen S, Alviar Kate Andre T, Arbilo Angel Nicole V, Choi Angelo Earvin Sy
Department of Chemical Engineering, De La Salle University, 2401 Taft Ave, Manila, 0922, Philippines.
Heliyon. 2024 Jun 5;10(11):e32346. doi: 10.1016/j.heliyon.2024.e32346. eCollection 2024 Jun 15.
Ultrasonic-assisted oxidative desulfurization (UAOD) is utilized to lessen environmental problems due to sulfur emissions. The process uses immiscible polar solvents and ultrasonic waves to enhance desulfurization efficiency. Prior research focused on comparing the effectiveness of UAOD for gasoline using response surface methodology. This study evaluates the desulfurization efficiency and operating costs, including ultrasonic power, irradiation time, and oxidant amount to determine optimal conditions. The study used a multi-objective fuzzy optimization (MOFO) approach to evaluate the economic viability of UAOD for gasoline. It identified upper and lower boundaries and then optimized the desulfurization efficiency and operating costs while considering uncertainty errors. The fuzzy model employed max-min aggregation to optimize the degree of satisfaction on a scale from 0 (unsatisfied) to 1 (satisfied). Optimal conditions for gasoline UAOD were found at 445.43 W ultrasonic power, 4.74 min irradiation time, and 6.73 mL oxidant, resulting in a 66.79 % satisfaction level. This yielded a 78.64 % desulfurization efficiency (Y) at an operating cost of 13.49 USD/L. Compared to existing literature, gasoline desulfurization was less efficient and less costly. The solutions provided by MOFO demonstrate not only economic viability through decreased overall operating costs and simplified process conditions, but also offer valuable insights for optimizing prospective future industrial-scale UAOD processes.
超声辅助氧化脱硫(UAOD)被用于减轻因硫排放造成的环境问题。该工艺使用不互溶的极性溶剂和超声波来提高脱硫效率。先前的研究集中于使用响应面法比较UAOD对汽油的脱硫效果。本研究评估了脱硫效率和运行成本,包括超声功率、辐照时间和氧化剂用量,以确定最佳条件。该研究采用多目标模糊优化(MOFO)方法来评估UAOD对汽油的经济可行性。它确定了上下限,然后在考虑不确定误差的情况下优化了脱硫效率和运行成本。模糊模型采用最大-最小聚合来优化满意度,满意度范围从0(不满意)到1(满意)。汽油UAOD的最佳条件为超声功率445.4W、辐照时间4.74分钟和氧化剂6.73mL,满意度为66.79%。这在运行成本为13.49美元/升的情况下产生了78.64%的脱硫效率(Y)。与现有文献相比,汽油脱硫效率较低且成本较低。MOFO提供的解决方案不仅通过降低总体运行成本和简化工艺条件证明了经济可行性,还为优化未来潜在的工业规模UAOD工艺提供了有价值的见解。