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利用不同生产方法从各种低成本海洋废物中生产生物炭:生物炭和海洋原料的特性及其在农业中的应用。

Biochar production from various low-cost marine wastes using different production methods: Characterization of biochar and marine feedstock for agricultural purposes.

机构信息

Çanakkale Onsekiz Mart University, Agricultural Faculty, Soil Science and Plant Nutrition Department, 17020 Çanakkale, Türkiye.

出版信息

Mar Pollut Bull. 2024 Aug;205:116623. doi: 10.1016/j.marpolbul.2024.116623. Epub 2024 Jul 3.

Abstract

Studies on the conversion of organic materials into biochar have been preferred due to the effectiveness of biochar. Aquatic ecosystems harbor a significant amount of organic biomass, much of which is transferred to terrestrial systems, but often remains as waste. In this study, Posidonia oceanica (PO), Halidrys siliquosa (HS), Ulva lactuca (UL), and Codium fragile (CF), commonly found as marine waste along coastlines globally, were used as feedstocks for biochar production under four different pyrolysis conditions. Several analyses were conducted to characterize both marine waste and biochar forms in order to evaluate their potential for agricultural applications. The results showed that marine wastes and biochars contain almost all the necessary nutrients required for plant nutrition in varying proportions. The CF feedstock has a higher nitrogen (N) content than other feedstocks, while the UL contains greater phosphorus (P), potassium (K), and magnesium (Mg). Additionally, the PO exhibits high calcium (Ca), boron (B), and manganese (Mn) contents. Carbon (C) content also varied significantly depending on the biochar production technique. Temperature had a greater influence than holding time on the disparities in the elemental composition of biochars. The pH values of all types of biochar increased with rising temperature. However, the electrical conductivity (EC) values of HS and PO biochars decreased with increasing temperature. The highest mean BET surface area was observed in PO biochars. However, UL biochar has the most significant proportional increase compared to the UL feedstock by 218 times. All characteristics determined for all materials (feedstock, biochar) were within acceptable limits for application to soil. In conclusion, both marine waste and biochar forms may be confidently used for agricultural purposes, particularly in soil applications, when considering the characterization parameters within the scope of this research. Additionally, supporting and developing these results with more comprehensive analysis and research would be more suitable to reveal the potential of these marine wastes for agricultural systems.

摘要

本研究以波西多尼亚海草(Posidonia oceanica,PO)、刚毛藻(Halidrys siliquosa,HS)、绿藻(Ulva lactuca,UL)和马尾藻(Codium fragile,CF)等在全球沿海地区常见的海洋废弃物为原料,在四种不同的热解条件下制备生物炭,对有机材料转化为生物炭的研究备受关注,主要是因为生物炭的有效性。水生生态系统中蕴藏着大量的有机生物质,其中很大一部分转移到陆地系统,但通常作为废弃物留存。通过对海洋废弃物和生物炭进行特性分析,评估其在农业应用方面的潜力。结果表明,海洋废弃物和生物炭都含有植物营养所需的几乎所有必要养分,只是比例有所不同。CF 原料的氮(N)含量高于其他原料,而 UL 则含有更多的磷(P)、钾(K)和镁(Mg)。此外,PO 表现出较高的钙(Ca)、硼(B)和锰(Mn)含量。碳(C)含量也因生物炭生产技术的不同而有显著差异。温度对生物炭元素组成差异的影响大于保温时间。所有类型生物炭的 pH 值均随温度升高而升高。然而,HS 和 PO 生物炭的电导率(EC)值随温度升高而降低。PO 生物炭的比表面积均值最高。但是,与 UL 原料相比,UL 生物炭的比例增加了 218 倍。所有材料(原料、生物炭)的特性均在适用于土壤的可接受范围内。综上所述,在考虑本研究范围内的特性参数的情况下,海洋废弃物和生物炭形式都可以有信心地用于农业用途,特别是在土壤应用方面。此外,通过更全面的分析和研究来支持和发展这些结果,更有助于揭示这些海洋废弃物在农业系统中的潜力。

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