Ghaware Rachana C, Birajdar Nagesh B, Kamble Ganesh S, Kolekar Sanjay S
Analytical Chemistry and Material Science Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur 416004, Maharashtra, India.
Langmuir. 2024 Jul 16;40(28):14426-14439. doi: 10.1021/acs.langmuir.4c01136. Epub 2024 Jul 8.
The current study mainly concentrates on the photocatalytic activity of composite nanomaterial of BiVO (BVO), NiFeO (NFO), and BiVO-NiFeO (BVO-NFO) under visible light. Among these, BVO-NFO composite degrades crystal violet dye within 60 min with a percentage degradation of 95.65% under visible light illumination. The BVO-NFO composite exhibits better photodegradation performance, which can be attributed to the effective light absorption and reduced recombination of the photoexcited charge carriers. Additionally, by applying a magnetic field, the BVO-NFO composite can be magnetically recovered by using the magnet for subsequent recycling. The synthesized composite was characterized using optical techniques like X-ray diffraction, ultraviolet diffuse reflectance spectroscopy, scanning electron microscopy, Brunauer-Emmett-Teller, and energy dispersive X-ray analysis. The effect of dye, before and after degradation, on vital organs of fish species was examined such as fish gill (pulmonary-toxicity), fish liver (hepato-toxicity), fish kidney (renal toxicity), fish brain (neural toxicity), and fish muscle (myopathy). This work offers a clear and practical method for designing a highly crystalline semiconductor photocatalyst for dye degradation and the remediation of industrial wastewater.
当前的研究主要集中在BiVO(BVO)、NiFeO(NFO)和BiVO-NiFeO(BVO-NFO)复合纳米材料在可见光下的光催化活性。其中,BVO-NFO复合材料在可见光照射下60分钟内可降解结晶紫染料,降解率为95.65%。BVO-NFO复合材料表现出更好的光降解性能,这可归因于有效的光吸收和光激发电荷载流子复合的减少。此外,通过施加磁场,BVO-NFO复合材料可以用磁铁进行磁回收以便后续循环利用。使用X射线衍射、紫外漫反射光谱、扫描电子显微镜、布鲁诺尔-埃米特-泰勒法和能量色散X射线分析等光学技术对合成的复合材料进行了表征。研究了染料降解前后对鱼类重要器官的影响,如鱼鳃(肺毒性)、鱼肝(肝毒性)、鱼肾(肾毒性)、鱼脑(神经毒性)和鱼肉(肌病)。这项工作为设计用于染料降解和工业废水修复的高结晶度半导体光催化剂提供了一种清晰且实用的方法。