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以乙二胺四乙酸锌（II）配合物为有效多相催化剂用于汉茨希合成多氢喹啉的胺功能化MIL-101（Cr）金属有机框架的合成后修饰

Postsynthetic Modification of Amine-Functionalized MIL-101(Cr) Metal-Organic Frameworks with an EDTA-Zn(II) Complex as an Effective Heterogeneous Catalyst for Hantzsch Synthesis of Polyhydroquinolines.

作者信息

Nikseresht Ahmad, Ghoochi Fatemeh, Mohammadi Masoud

机构信息

Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Iran.

Department of Chemistry, Faculty of Science, Ilam University, 69315-516 Ilam, Iran.

出版信息

ACS Omega. 2024 Jun 21;9(26):28114-28128. doi: 10.1021/acsomega.4c01117. eCollection 2024 Jul 2.

DOI:10.1021/acsomega.4c01117
PMID:38973916
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11223138/
Abstract

The present work aims at preparing the EDTA-Zn(II) complex-supported on the amine-functionalized MIL-101(Cr) MOF-as a new and effective heterogenized catalyst. The optimization of the hydrothermal process shows that 120 °C is the best condition to grow the MIL-101(Cr)-NH MOF crystals. Moreover, regarding the use of the postsynthetic modification (PSM) method, hexadentate EDTA was grafted on this support via a simple aminolysis process before further coordinating it with Zn ions to create the corresponding Zn(II) catalytic complex. The catalytic activity of this compound was then investigated in the context of a one-pot synthesis of polyhydroquinolines. This approach has a number of advantages including the following: the use of a solvent that is not hazardous, applying a porous catalyst that is inexpensive, secure, and recyclable; rapid reaction times, high levels of efficiency, and the simplicity of MOF catalyst separation. Accordingly, the process in question can be given the label of "green chemistry".

摘要

本研究旨在制备负载于胺功能化MIL-101(Cr)金属有机框架（MOF）上的乙二胺四乙酸锌（II）配合物，作为一种新型高效的多相催化剂。水热过程的优化表明，120°C是生长MIL-101(Cr)-NH MOF晶体的最佳条件。此外，关于后合成修饰（PSM）方法的应用，通过简单的氨解过程将六齿乙二胺四乙酸接枝到该载体上，然后使其与锌离子进一步配位以生成相应的锌（II）催化配合物。然后在一锅法合成聚氢喹啉的背景下研究了该化合物的催化活性。这种方法具有许多优点，包括：使用无害溶剂、应用廉价、安全且可回收的多孔催化剂；反应时间短、效率高以及MOF催化剂分离简单。因此，该过程可被称为“绿色化学”。

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