六氯铊酸盐在氯化铯 - 磷钨酸盐晶格Cs(TlCl)(PWO)·9CsCl中的晶体结构。
Crystal structure of hexa-chloro-thallate within a caesium chloride-phospho-tungstate lattice Cs(TlCl)(PWO)·9CsCl.
作者信息
Deblonde Gauthier, Colliard Ian
机构信息
Physical and Life Sciences Directorate Glenn T Seaborg Institute Lawrence Livermore National Laboratory,Livermore California 94550 USA.
出版信息
Acta Crystallogr E Crystallogr Commun. 2024 Jun 14;80(Pt 7):721-724. doi: 10.1107/S2056989024005565. eCollection 2024 Jun 1.
Crystal formation of caesium thallium chloride phospho-tungstates, Cs(TlCl)(PWO)·9CsCl showcases the ability to capture and crystallize octa-hedral complexes the use of polyoxometalates (POMs). The large number of caesium chlorides allows for the POM [α-PWO] to arrange itself in a cubic close-packing lattice extended framework, in which the voids created enable the capture of the [TlCl] complex.
铯铊氯磷钨酸盐Cs(TlCl)(PWO)·9CsCl的晶体形成展示了利用多金属氧酸盐（POMs）捕获八面体配合物并使其结晶的能力。大量的氯化铯使得POM [α-PWO] 能够排列成一个立方密堆积晶格扩展框架，其中形成的空隙能够捕获 [TlCl] 配合物。
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