三乙腈 -（1,4,7 - 三甲基 - 1,4,7 - 三氮杂环壬烷）钴（II）双（四苯基硼酸盐）
Triaceto-nitrile-(1,4,7-trimethyl-1,4,7-tri-aza-cyclonona-ne)cobalt(II) bis-(tetra-phenyl-borate).
作者信息
Shin Jeongcheol, Kim Jin, Choi Jonghoon
机构信息
Department of Chemistry Duksung Women's University Seoul 01369 Republic of Korea.
Department of Chemistry, Sunchon National University, Sunchon 57922, Republic of Korea.
出版信息
IUCrdata. 2024 Jun 11;9(Pt 6):x240539. doi: 10.1107/S241431462400539X. eCollection 2024 Jun.
The title cobalt(II) complex, Co(CHN)(CHN) or [(tacn)Co(NCMe)][BPh], has been characterized by single-crystal X-ray diffraction. It incorporates the well-known macrocyclic tacn (1,4,7-trimethyl-1,4,7-tri-aza-cyclo-nona-ne) ligand, which is coordinated facially to the metal center. The complex crystallizes in space group 2/ with = 4. The divalent cobalt ion exhibits a six-coordinate octa-hedral geometry by one tacn and three aceto-nitrile ligands. Two non-coordinating tetra-phenyl-borate (BPh ) anions are also present.
标题钴（II）配合物Co(CHN)(CHN)或[(tacn)Co(NCMe)][BPh]已通过单晶X射线衍射进行了表征。它包含著名的大环tacn（1,4,7-三甲基-1,4,7-三氮杂环壬烷）配体，该配体以面式方式与金属中心配位。该配合物结晶于空间群2/，a = 4。二价钴离子通过一个tacn和三个乙腈配体呈现六配位八面体几何构型。还存在两个非配位的四苯基硼酸根（BPh）阴离子。
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