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从铅笔芯中电化学剥离石墨烯

Electrochemical exfoliation of graphene from pencil lead.

作者信息

Jiwarawat Natchanon, Leukulwatanachai Thapan, Subhakornphichan Kunbhass, Limwathanagura Siwagorn, Wanotayan Sittinadh, Atthi Nithi, Pankiew Apirak, Pungetmongkol Porpin

机构信息

International School of Engineering, Nano-Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, 10330, Thailand.

Department of Chemical Engineering, Bio-Circular-Green-economy Technology & Engineering Center, BCGeTEC, Chulalongkorn University, Bangkok, 10330, Thailand.

出版信息

Sci Rep. 2024 Jul 10;14(1):15892. doi: 10.1038/s41598-024-66825-0.

Abstract

Addressing an ever-increasing demand for graphene in recent years, simple, accessible, and effective graphene synthesis methods are essential. One of such methods is to use a highly oriented pyrolytic graphite (HOPG) to perform an electrochemical exfoliation. While this is one of the simplest and most cost-effective methods, the limited availability and price of HOPG hinders its usage. Our study proposed a simple and economical electrochemical exfoliation of pencil lead, producing graphene with properties comparable to that produced from HOPG. The electrical properties are determined by depositing graphene onto a screen-printed electrode. Graphene from pencil leads can achieve an electrical resistance as low as 1.86 kΩ, marking over 80% improvement in electrical performance compared to bare electrodes. This finding provides an alternative for the synthesis of graphene, increasing its availability and the cost-effectiveness as well as contributing towards a potential commercialization of the method in the future.

摘要

为满足近年来对石墨烯不断增长的需求,简单、易操作且有效的石墨烯合成方法至关重要。其中一种方法是使用高度取向热解石墨(HOPG)进行电化学剥离。虽然这是最简单且最具成本效益的方法之一,但HOPG的有限可用性和价格阻碍了其使用。我们的研究提出了一种简单且经济的铅笔芯电化学剥离方法,所生产的石墨烯具有与HOPG生产的石墨烯相当的性能。通过将石墨烯沉积在丝网印刷电极上来测定其电学性能。铅笔芯制成的石墨烯可实现低至1.86 kΩ的电阻,与裸电极相比,电学性能提高了80%以上。这一发现为石墨烯的合成提供了一种替代方法,提高了其可用性和成本效益,并为该方法未来的潜在商业化做出了贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b72/11236967/5abe8165745e/41598_2024_66825_Fig1_HTML.jpg

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