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不同增容剂对 Bambusa Vulgaris 竹纤维增强绿色低密度聚乙烯复合材料性能的影响。

Effect of Different Compatibilizers on the Properties of Green Low-Density Polyethylene Composites Reinforced with Bambusa Vulgaris Bamboo Fibers.

作者信息

Bosenbecker Mariane W, Silva Eduarda Vieira, Paganotto Gian Francesco Dos Reis, Zanon Tiago Thomaz Migliati, Langone Fernanda, Rodrigues Marlon Bender Bueno, Marini Juliano, Labidi Jalel, Missio André Luiz, de Oliveira Amanda Dantas

机构信息

Technological Development Center-CDTec, Postgraduate Program in Materials Science and Engineering-PPGCEM/UFPEL, Federal University of Pelotas-UFPel, Pelotas 96010-610, RS, Brazil.

Department of Materials Engineering-DEMa, Federal University of São Carlos-UFSCar, São Carlos 13565-905, SP, Brazil.

出版信息

Polymers (Basel). 2024 Jun 21;16(13):1760. doi: 10.3390/polym16131760.

Abstract

Low-density green polyethylene (LDGPE) composites reinforced with 5 wt% of bamboo fiber and 3 wt% of a compatibilizing agent (polyethylene grafted with maleic anhydride and tannin) were processed through extrusion and injection molding. Bamboo fiber, Bambusa Vulgaris, was characterized using Fourier-transform infrared spectroscopy (FTIR). The molded specimens were analyzed for their thermal, mechanical, and morphological properties. The estimated concentration was chosen to provide the best mechanical strength to the material studied. FTIR analysis of the fibers revealed the presence of groups characteristic of bamboo fiber and tannin. Differential scanning calorimetry revealed that both compatibilizing agents increased the matrix's degree of crystallinity. However, scanning electron microscopy (SEM) showed that, despite the presence of compatibilizing agents, there was no significant improvement in adhesion between the bamboo fibers and LDGPE.

摘要

采用挤出和注塑工艺制备了分别添加5 wt%竹纤维和3 wt%增容剂(马来酸酐接枝聚乙烯和单宁)增强的低密度绿色聚乙烯(LDGPE)复合材料。使用傅里叶变换红外光谱(FTIR)对竹纤维(巨龙竹)进行了表征。对模塑试样的热性能、力学性能和形态进行了分析。选择估计的浓度是为了使所研究的材料具有最佳的机械强度。纤维的FTIR分析揭示了竹纤维和单宁的特征基团的存在。差示扫描量热法表明,两种增容剂均提高了基体的结晶度。然而,扫描电子显微镜(SEM)显示,尽管存在增容剂,但竹纤维与LDGPE之间的粘附性没有显著改善。

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