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热冲击条件对3D打印材料(丙烯腈-丁二烯-苯乙烯、丙烯腈-苯乙烯-丙烯酸酯、高抗冲聚苯乙烯和聚乳酸)低周疲劳性能的影响

Effect of Thermal Shock Conditions on the Low-Cycle Fatigue Performance of 3D-Printed Materials: Acrylonitrile Butadiene Styrene, Acrylonitrile-Styrene-Acrylate, High-Impact Polystyrene, and Poly(lactic acid).

作者信息

Głowacki Marcin, Mazurkiewicz Adam, Skórczewska Katarzyna, Lewandowski Krzysztof, Smyk Emil, Branco Ricardo

机构信息

Faculty of Mechanical Engineering, Bydgoszcz University of Science and Technology, Kaliskiego 7 Street, 85-796 Bydgoszcz, Poland.

Faculty of Chemical Technology and Engineering, Bydgoszcz University of Science and Technology, Seminaryjna 3 Street, 85-326 Bydgoszcz, Poland.

出版信息

Polymers (Basel). 2024 Jun 27;16(13):1823. doi: 10.3390/polym16131823.

Abstract

3D printing technology is becoming a widely adopted alternative to traditional polymer manufacturing methods. The most important advantage of 3D printing over traditional manufacturing methods, such as injection molding or extrusion, is the short time from the creation of a new design to the finished product. Nevertheless, 3D-printed parts generally have lower strength and lower durability compared to the same parts manufactured using traditional methods. Resistance to the environmental conditions in which a 3D-printed part operates is important to its durability. One of the most important factors that reduces durability and degrades the mechanical properties of 3D-printed parts is temperature, especially rapid temperature changes. In the case of inhomogeneous internal geometry and heterogeneous material properties, rapid temperature changes can have a significant impact on the degradation of 3D-printed parts. This degradation is more severe in high-humidity environments. Under these complex service conditions, information on the strength and fatigue behavior of 3D-printed polymers is limited. In this study, we evaluated the effects of high humidity and temperature changes on the durability and strength properties of 3D-printed parts. Samples made of commonly available materials such as ABS (Acrylonitrile Butadiene Styrene), ASA (Acrylonitrile-Styrene-Acrylate), HIPS (High-Impact Polystyrene), and PLA (Poly(lactic acid)) were subjected to temperature cycling, from an ambient temperature to -20 °C, and then were heated to 70 °C. After thermal treatment, the samples were subjected to cyclic loading to determine changes in their fatigue life relative to non-thermally treated reference samples. The results of cyclic testing showed a decrease in durability for samples made of ASA and HIPS. The ABS material proved to be resistant to the environmental effects of shocks, while the PLA material exhibited an increase in durability. Changes in the internal structure and porosity of the specimens under temperature changes were also evaluated using microcomputed tomography (microCT). Temperature changes also affected the porosity of the samples, which varied depending on the material used.

摘要

3D打印技术正成为一种广泛采用的替代传统聚合物制造方法的技术。与传统制造方法(如注塑成型或挤出成型)相比,3D打印最重要的优势在于从新设计创建到成品的时间短。然而,与使用传统方法制造的相同部件相比,3D打印部件的强度和耐用性通常较低。3D打印部件运行所处环境条件的耐受性对其耐用性很重要。降低3D打印部件耐用性并使其机械性能下降的最重要因素之一是温度,尤其是快速的温度变化。在内部几何形状不均匀和材料特性各异的情况下,快速的温度变化会对3D打印部件的降解产生重大影响。在高湿度环境中,这种降解更为严重。在这些复杂的使用条件下,关于3D打印聚合物强度和疲劳行为的信息有限。在本研究中,我们评估了高湿度和温度变化对3D打印部件耐用性和强度性能的影响。由常见材料(如ABS(丙烯腈 - 丁二烯 - 苯乙烯)、ASA(丙烯腈 - 苯乙烯 - 丙烯酸酯)、HIPS(高抗冲聚苯乙烯)和PLA(聚乳酸))制成的样品经历了温度循环,从环境温度到 -20°C,然后加热到70°C。热处理后,对样品进行循环加载,以确定其相对于未经热处理的参考样品的疲劳寿命变化。循环测试结果表明,由ASA和HIPS制成的样品耐用性下降。ABS材料被证明能抵抗冲击的环境影响,而PLA材料的耐用性有所提高。还使用微型计算机断层扫描(microCT)评估了温度变化下试样内部结构和孔隙率的变化。温度变化也影响了样品的孔隙率,孔隙率因所用材料而异。

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