客体蒸汽存在下，含镁的坚固阴离子金属有机框架中具有高离子传导性。
High ionic conduction in a robust anionic metal-organic framework containing Mg under guest vapors.
作者信息
Niwa Shintaro, Hashimoto Shuhei, Chen Duotian, Toyao Takashi, Shimizu Ken-Ichi, Sadakiyo Masaaki
机构信息
Department of Applied Chemistry, Faculty of Science Division I, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
Institute for Catalysis, Hokkaido University, Sapporo, Hokkaido 001-0021, Japan.
出版信息
Dalton Trans. 2024 Jul 23;53(29):12043-12046. doi: 10.1039/d4dt01331j.
We report on the synthesis and high ionic conductivity of a highly crystalline Mg-containing metal-organic framework (MOF) with Type A feature (, anionic framework having Mg as a counter cation). We synthesized Mg[Zr(CHO)] (SU-102-Mg) through ion exchange reaction. SU-102-Mg showed a high ionic conductivity of 3.6 × 10 S cm (25 °C, under MeCN vapor).
我们报道了一种具有A型特征（以镁作为抗衡阳离子的阴离子骨架）的高结晶度含镁金属有机框架（MOF）的合成及其高离子电导率。我们通过离子交换反应合成了Mg[Zr(CHO)]（SU-102-Mg）。SU-102-Mg在25℃、乙腈蒸汽条件下表现出3.6×10 S cm的高离子电导率。
Zotero 插件