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采用湿化学法在尼龙上制备用于发电机的高功率因数柔性AgTe薄膜。

High Power Factor Flexible AgTe Film on Nylon by a Wet Chemical Method for Power Generator.

作者信息

Wu Changxuan, Liu Ying, Li Jiajia, Zhang Mingcheng, Wang Zixing, Cai Kefeng

机构信息

Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science & Engineering, Tongji University, 4800 Caoan Road, Shanghai 201804, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2024 Jul 31;16(30):39623-39630. doi: 10.1021/acsami.4c07332. Epub 2024 Jul 16.

Abstract

Herein, we develop a facile wet chemical method for the synthesis of AgTe powders at room temperature and flexible AgTe/nylon thermoelectric (TE) films are prepared by vacuum-assisted filtration of the synthesized AgTe powders and then hot pressing. Because of the good crystallinity of AgTe grains and continuous grain boundaries, an optimized film exhibits a power factor of 513 μW m K at 300 K, which stands among the highest values reported for AgTe-based films to date. In addition, the film also has good flexibility. A four-leg flexible TE device assembled with the film generates a power density of 5.46 W m at a temperature gradient of 31.8 K. This work provides a facile and environmentally friendly method for preparing flexible AgTe films.

摘要

在此,我们开发了一种简便的湿化学方法,用于在室温下合成AgTe粉末,并通过对合成的AgTe粉末进行真空辅助过滤然后热压来制备柔性AgTe/尼龙热电(TE)薄膜。由于AgTe晶粒具有良好的结晶性和连续的晶界,优化后的薄膜在300 K时的功率因子为513 μW m⁻² K⁻²,这是迄今为止报道的基于AgTe的薄膜中的最高值之一。此外,该薄膜还具有良好的柔韧性。用该薄膜组装的四腿柔性TE器件在31.8 K的温度梯度下产生的功率密度为5.46 W m⁻²。这项工作为制备柔性AgTe薄膜提供了一种简便且环保的方法。

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