Chen Hsueh-Shih, Patidar Kapil, Chen Pen-Ru
Department of Materials Science & Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan.
College of Semiconductor Research, National Tsing Hua University, Hsinchu 30013, Taiwan.
Nanomaterials (Basel). 2025 Jul 26;15(15):1156. doi: 10.3390/nano15151156.
In this study, we report the synthesis of Te and AgTe micron-sized rods (MRs) via a controlled hot-injection-based quenching process, enabling the control of rod morphology and enhanced crystallinity. Structural analysis confirmed that the synthesized Te MRs exhibit a trigonal phase, growing along the (110) direction, while AgTe MRs undergo a phase transformation into a monoclinic structure upon Ag doping. A simple and scalable photodetector (PD) was fabricated by drop-casting Te and AgTe MRs onto PET plastic films, followed by the application of Ag paste electrodes. The PD demonstrated room-light-induced photocurrent responses, which increased significantly upon mechanical bending due to the formation of additional conductive pathways between MRs. The AgTe-based bending sensor exhibited a fivefold enhancement in photocurrent compared to its Te counterpart and maintained high stability over 1000 bending cycles. These results highlight the potential of Te and AgTe MRs for use in flexible and wearable motion-sensing technologies, offering a simple yet effective approach for integrating 1D telluride nanostructures into scalable optoelectronic applications.
在本研究中,我们报道了通过基于热注入的可控淬火过程合成碲(Te)和碲化银(AgTe)微米级棒(MRs),从而能够控制棒的形态并提高结晶度。结构分析证实,合成的碲MRs呈现三角相,沿(110)方向生长,而碲化银MRs在银掺杂后发生相变形成单斜结构。通过将碲和碲化银MRs滴铸到聚对苯二甲酸乙二酯(PET)塑料薄膜上,随后施加银浆电极,制备了一种简单且可扩展的光电探测器(PD)。该PD表现出室内光诱导的光电流响应,由于MRs之间形成了额外的导电路径,在机械弯曲时光电流显著增加。与基于碲的弯曲传感器相比,基于碲化银的弯曲传感器的光电流增强了五倍,并且在1000次弯曲循环中保持了高稳定性。这些结果突出了碲和碲化银MRs在柔性和可穿戴运动传感技术中的应用潜力,为将一维碲化物纳米结构集成到可扩展的光电子应用中提供了一种简单而有效的方法。