Iqbal Saman, Rafique Muhammad Shahid, Iqbal Nida, Bashir Shazia, Malarvili M B, Anjum Aftab Ahmad
Department of Physics, University of the Punjab, Lahore, Pakistan.
Department of Physics, University of Engineering and Technology, Lahore, Pakistan.
Heliyon. 2024 Jun 18;10(12):e33270. doi: 10.1016/j.heliyon.2024.e33270. eCollection 2024 Jun 30.
This research paper reports an enhancement of thermal, optical, mechanical and antibacterial activities of the Polyvinyl alcohol-Nanodiamonds (PVA-NDs) composite required for the food packaging industry. The synthesis of composites was done by the wet processing method. The large surface area of NDs facilitated the robust interaction between the hydroxyl group and macromolecular chains of PVA to enhance the hydrogen bonding of PVA with NDs rather than PVA molecules. Thus, a reduction in PVA diffraction peak intensity was reported. NDs improved the thermal stability by preventing the out-diffusion of volatile decomposition products of PVA. The results also revealed an enhancement in tensile strength (∼60 MPa) and ductility (∼180 %). PVA-NDs composite efficiently blocked the UVC (100 %), most of the part of the UVB (∼85 % above 300 nm), and UVA (∼58 %). Furthermore, enhanced antibacterial activities were reported for PVA-NDs composite against and . NDs accumulated around the bacterial cells prevented essential cellular functions and led to death. Hence, this composite could be a promising candidate for safe, thermally stable, strong, flexible, transparent, UV- resistant antibacterial food packaging material.
本研究论文报道了食品包装行业所需的聚乙烯醇-纳米金刚石(PVA-NDs)复合材料的热、光学、机械和抗菌活性的增强。复合材料通过湿法工艺合成。纳米金刚石的大表面积促进了羟基与聚乙烯醇大分子链之间的强相互作用,增强了聚乙烯醇与纳米金刚石而非聚乙烯醇分子之间的氢键。因此,报道了聚乙烯醇衍射峰强度的降低。纳米金刚石通过防止聚乙烯醇挥发性分解产物的向外扩散提高了热稳定性。结果还显示拉伸强度(约60MPa)和延展性(约180%)有所增强。PVA-NDs复合材料有效地阻挡了UVC(100%)、大部分UVB(300nm以上约85%)和UVA(约58%)。此外,报道了PVA-NDs复合材料对[具体细菌名称1]和[具体细菌名称2]的抗菌活性增强。聚集在细菌细胞周围的纳米金刚石阻止了基本的细胞功能并导致死亡。因此,这种复合材料有望成为安全、热稳定、坚固、柔韧、透明、抗紫外线的抗菌食品包装材料。