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研究柳树和柽柳属植物在废水中去除亚甲基蓝和土壤中重金属修复方面的能力。

Investigation of Eucalyptus camaldulensis and Tamarix aphylla species' capacities for methylene blue removal in wastewater and heavy metal remediation in soil.

机构信息

Agriculture and Natural Resources Department, Ardakan University, Yazd, Iran.

Department of Nature Engineering, Faculty of Agriculture & Natural Resources, Ardakan University, P.O. Box 184, Ardakan, Iran.

出版信息

Environ Monit Assess. 2024 Jul 20;196(8):754. doi: 10.1007/s10661-024-12903-9.

Abstract

In the contemporary landscape, the reuse of wastewater holds paramount significance. Concurrently, wastewater carries an array of pollutants encompassing chemical dyes and heavy metals. This study delves into the potential of Tamarix aphylla (TA) and Eucalyptus camaldulensis (EC) species for mitigating heavy metals in soil and eliminating methylene blue dye (MB) from wastewater. The research begins with assessing the dye adsorption process, considering pivotal factors such as initial pH, adsorbent dosage, initial dye concentration, and contact time. Outcomes reveal EC's superiority in dye removal compared to TA. As a bioremediation agent, EC exhibits a 90.46% removal efficacy for MB within 15 min, with pH 7.0 as the operative condition. Equilibrium analysis employs Temkin (T), Freundlich (F), and Langmuir (L) isotherms, revealing an excellent fit with the L isotherm model. The study delves further by probing surface adsorption kinetics through pseudo-first-order (PFO) and pseudo-second-order (PSO) models. Furthermore, to discern the divergent impacts of EC and TA on soil heavy metal reduction, soil samples were collected from three distinct zones: an untouched control area, alongside areas where EC and TA were cultivated at the Yazd wastewater site in Iran. Heavy metal levels in the soil were meticulously assessed through rigorous measurement and statistical scrutiny. The findings spotlight TA-cultivated soil as having the highest levels across all examined factors. Ultimately, EC emerges as the superior contender, proficiently excelling in both MB eliminations from wastewater and heavy metal amelioration in the soil, positioning it as the preferred phytoremediation agent.

摘要

在当代环境下,废水再利用具有至关重要的意义。与此同时,废水中携带着大量的污染物,包括化学染料和重金属。本研究探讨了柽柳(TA)和桉树(EC)物种在减轻土壤重金属和去除废水中亚甲基蓝染料(MB)方面的潜力。该研究首先评估了染料吸附过程,考虑了初始 pH 值、吸附剂用量、初始染料浓度和接触时间等关键因素。结果表明,EC 在去除染料方面优于 TA。作为一种生物修复剂,EC 在 15 分钟内对 MB 的去除效率达到 90.46%,最佳条件为 pH 值 7.0。平衡分析采用 Temkin(T)、Freundlich(F)和 Langmuir(L)等温线,结果表明与 L 等温线模型拟合度较好。研究还通过探究伪一级(PFO)和伪二级(PSO)模型的表面吸附动力学,进一步深入研究。此外,为了探究 EC 和 TA 对土壤重金属还原的不同影响,从伊朗亚兹德废水场的未受干扰的对照区以及 EC 和 TA 种植区采集了土壤样本。通过严格的测量和统计分析,对土壤中的重金属含量进行了评估。研究结果突出表明,在所有受检因素中,种植柽柳的土壤中重金属含量最高。最终,EC 脱颖而出,在从废水中去除 MB 和改善土壤中的重金属方面都表现出色,成为首选的植物修复剂。

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