Yue Wei, Wang Bing
Zhejiang College of Security Technology, Wenzhou, Zhejiang, China.
Sci Prog. 2024 Jul-Sep;107(3):368504241266559. doi: 10.1177/00368504241266559.
Ceramic-added air lime mortars have been used since ancient times owing to the pozzolanic effect provided by crushed ceramic particles that impart hydraulic properties. This work reviews the historical use, composition, reaction mechanisms, characterization techniques, and performance properties of ceramic-added air lime mortars. The fine ceramic powder composed of silica and alumina phases reacts with calcium hydroxide released during lime hydration to form calcium silicate hydrates (CSH) and calcium aluminate hydrates (CAH) via pozzolanic reaction. This provides hydraulicity and reduces setting time compared to pure air lime mortars. The coarser ceramic particles also serve as aggregate and refine the microstructure as filler. The reactivity depends on the ceramic composition, amorphous phase content, particle size distribution, and firing temperature. Optimal proportioning of the fine ceramic powder and coarse ceramic aggregate is necessary to achieve desired properties. Ceramic addition enhances the durability of air lime mortars against weathering while maintaining compatibility with lime-based masonry structures. Key novelties of this review include: (i) in-depth analysis of the influence of ceramic characteristics (mineralogy, particle size, pozzolanicity) and processing on reaction kinetics and phase evolution; (ii) systematic assessment of mechanical, physical and durability properties in comparison to conventional air lime mortars and cement-based grouts; (iii) elucidation of microstructural mechanisms governing performance using advanced characterization techniques; (iv) critical appraisal of test methods and standards for evaluation; and (v) rigorous discussion on potential applications in construction, conservation and repair, with case studies.
由于粉碎的陶瓷颗粒具有火山灰效应,能赋予水硬性,添加陶瓷的气硬性石灰砂浆自古以来就被使用。本文综述了添加陶瓷的气硬性石灰砂浆的历史用途、成分、反应机理、表征技术和性能特性。由二氧化硅和氧化铝相组成的细陶瓷粉末与石灰水化过程中释放的氢氧化钙反应,通过火山灰反应形成硅酸钙水合物(CSH)和铝酸钙水合物(CAH)。与纯气硬性石灰砂浆相比,这提供了水硬性并缩短了凝结时间。较粗的陶瓷颗粒还作为骨料,起到填充作用,细化微观结构。反应活性取决于陶瓷成分、非晶相含量、粒度分布和烧制温度。为了获得所需性能,必须对细陶瓷粉末和粗陶瓷骨料进行优化配比。添加陶瓷提高了气硬性石灰砂浆的耐候性,同时保持了与石灰基砌体结构的相容性。本综述的主要新颖之处包括:(i)深入分析陶瓷特性(矿物学、粒度、火山灰活性)和加工对反应动力学和相演变的影响;(ii)与传统气硬性石灰砂浆和水泥基灌浆相比,系统评估机械、物理和耐久性性能;(iii)使用先进表征技术阐明控制性能的微观结构机制;(iv)对评估的测试方法和标准进行批判性评价;(v)通过案例研究,对在建筑、保护和修复中的潜在应用进行严格讨论。