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用于低功耗微电子设备的集成超级电容器的基于物联网的碳布基3D打印氢燃料电池。

IoT enabled carbon cloth-based 3D printed hydrogen fuel cell integrated with supercapacitor for low-power microelectronic devices.

作者信息

Vanmathi S, Awasthi Himanshi, Pal Abhishesh, Goel Sanket

机构信息

MEMS, Microfluidics and Nanoelectronics (MMNE) Lab, Birla Institute of Technology and Science (BITS) Pilani, Hyderabad Campus, Hyderabad, 500078, India.

Department of Electrical and Electronics Engineering, Birla Institute of Technology and Science (BITS) Pilani, Hyderabad Campus, Hyderabad, 500078, India.

出版信息

Sci Rep. 2024 Jul 23;14(1):16953. doi: 10.1038/s41598-024-67759-3.

DOI:10.1038/s41598-024-67759-3
PMID:39043777
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11266664/
Abstract

A Hydrogen fuel cell (HFC) broad range associated with Internet of Things (IoT) technologies that require slightly less and constant electricity made possible by remote climate monitoring connections. Novelty demonstrates a miniature HFC based on carbon cloth electrodes and sealing elements manufactured via 3D printing. Cobalt (II) Oxide (CoO)-reduced Graphene Oxide (rGO) and Platinum (Pt) based nanoparticles are coated over carbon cloth to increase the catalytic activity at the anode and cathode. Hydrogen is produced by using an aluminium foil (Al) that is stored in between the filter paper and through capillary action the sodium hydroxide pellets (NaOH) are applied and reacted with Al foil to produce hydrogen. The single HFC device working surface area of 1 × 1 cm effectively generates an open circuit voltage (OCV) of 1.3 V, a current density of 1.602 mA/cm, and a peak power density of 761 mW/cm. The fuel cell stability performance is monitored for up to 10 h. The power obtained from the HFC is stored in a supercapacitor and used to supply energy to the IoT component. The module includes a built-in sensor that monitors the temperature, pressure, and humidity. The measured data is then transmitted to a smartphone via Bluetooth.

摘要

氢燃料电池(HFC)与物联网(IoT)技术广泛相关,这些技术通过远程气候监测连接实现所需电量略少且恒定。创新性展示了一种基于碳布电极和通过3D打印制造的密封元件的微型氢燃料电池。氧化钴(II)(CoO)还原氧化石墨烯(rGO)和铂(Pt)基纳米颗粒涂覆在碳布上,以提高阳极和阴极的催化活性。通过使用储存在滤纸之间的铝箔(Al)产生氢气,并通过毛细作用施加氢氧化钠颗粒(NaOH),使其与铝箔反应产生氢气。单个氢燃料电池装置1×1平方厘米的工作表面积有效地产生了1.3V的开路电压(OCV)、1.602mA/cm的电流密度和761mW/cm的峰值功率密度。对燃料电池的稳定性性能进行了长达10小时监测。从氢燃料电池获得的电力存储在超级电容器中,并用于向物联网组件供电。该模块包括一个内置传感器,用于监测温度、压力和湿度。然后,测量数据通过蓝牙传输到智能手机。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/67e802b229ad/41598_2024_67759_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/8899febd89f4/41598_2024_67759_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/a23b0f984501/41598_2024_67759_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/cbabb9d066d2/41598_2024_67759_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/8822e9a4d150/41598_2024_67759_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/87ed1639db8b/41598_2024_67759_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/67e802b229ad/41598_2024_67759_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/8899febd89f4/41598_2024_67759_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/a23b0f984501/41598_2024_67759_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/cbabb9d066d2/41598_2024_67759_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/8822e9a4d150/41598_2024_67759_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/87ed1639db8b/41598_2024_67759_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77d8/11266664/67e802b229ad/41598_2024_67759_Fig9_HTML.jpg

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本文引用的文献

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Droplet-based lab-on-chip platform integrated with laser ablated graphene heaters to synthesize gold nanoparticles for electrochemical sensing and fuel cell applications.基于液滴的微流控芯片平台与激光烧蚀石墨烯加热器集成,用于合成金纳米粒子,用于电化学传感和燃料电池应用。
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