Webb Caleb Merrick, Stafford Charles Allen
Department of Physics, University of Arizona, Tucson, AZ 85721, USA.
Entropy (Basel). 2024 Jul 20;26(7):611. doi: 10.3390/e26070611.
We present a partition of quantum observables in an open quantum system that is inherited from the division of the underlying Hilbert space or configuration space. It is shown that this partition leads to the definition of an inhomogeneous continuity equation for generic, non-local observables. This formalism is employed to describe the local evolution of the von Neumann entropy of a system of independent quantum particles out of equilibrium. Crucially, we find that all local fluctuations in the entropy are governed by an entropy current operator, implying that the production of entanglement entropy is not measured by this partitioned entropy. For systems linearly perturbed from equilibrium, it is shown that this entropy current is equivalent to a heat current, provided that the system-reservoir coupling is partitioned symmetrically. Finally, we show that any other partition of the coupling leads directly to a divergence of the von Neumann entropy. Thus, we conclude that Hilbert-space partitioning is the only partition of the von Neumann entropy that is consistent with the laws of thermodynamics.
我们提出了一种开放量子系统中量子可观测量的划分,它源自基础希尔伯特空间或构型空间的划分。结果表明,这种划分导致了针对一般非局部可观测量的非均匀连续性方程的定义。这种形式体系被用于描述处于非平衡态的独立量子粒子系统的冯·诺依曼熵的局部演化。至关重要的是,我们发现熵的所有局部涨落都由一个熵流算符支配,这意味着纠缠熵的产生并非由这种划分后的熵来度量。对于从平衡态线性扰动的系统,结果表明,只要系统 - 储能器耦合是对称划分的,这种熵流就等同于热流。最后,我们表明耦合的任何其他划分都会直接导致冯·诺依曼熵的散度。因此,我们得出结论,希尔伯特空间划分是唯一与热力学定律一致的冯·诺依曼熵划分。