Characterization of on-road nitrogen oxides and black carbon emissions from high emitters of heavy-duty diesel vehicles in China.

Heavy-duty diesel vehicles (HDDVs) significantly contribute to atmospheric nitrogen oxides (NO) and black carbon (BC), with high emitters within the HDDV fleet impacting the total emissions. However, emission patterns and contributions of high emitters are rarely explored from a fleet-perspective. We investigated NO and BC emission factors (EFs) from 1925 HDDVs in Shenzhen by the plume-chasing method, and found that the fleet-average EFs decreased with stricter emission standards. Unexpectedly, the average NO EF for the China IV fleet was comparable with that for the China III fleet due to possible ineffective aftertreatment in high-emitter sectors of China IV HDDVs. Decreasing trend in average NO EF since 2017 reflected the effective emission controls by the implementation of China V standard. Besides, semi-trailer tractors exhibited a higher incidence of NO over-emissions, whereas BC high emitters were more pronounced in box trucks. Total NO and BC emissions from HDDVs in Shenzhen were revisited, reaching 54.0 and 1.1 Gg·yr, with updated NO EF correcting a 26.2 % underestimation in national guidelines. Notably, eliminating high emitters yields greater emission reduction benefits than merely retiring old HDDVs, with BC reduction outpacing NO. This study provides new insights into the implementation of targeted emission reduction measures for HDDVs.