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采用羧甲基魔芋葡甘聚糖接枝丙烯酸-丙烯酰胺/蒙脱土复合水凝胶高效去除碱性品红染料。

Highly effective removal of basic fuchsin dye using carboxymethyl konjac glucomannan grafted acrylic acid-acrylamide/montmorillonite composite hydrogel.

机构信息

Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science and Technology, Xi'an, Shaanxi 710021, PR China.

Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science and Technology, Xi'an, Shaanxi 710021, PR China.

出版信息

Int J Biol Macromol. 2024 Oct;277(Pt 1):134163. doi: 10.1016/j.ijbiomac.2024.134163. Epub 2024 Jul 24.

Abstract

This study developed a nanocomposite hydrogel, CAM4-MMT, for efficiently removing basic fuchsin dye from water. The hydrogel was prepared by grafting a copolymer of acrylic acid (AA) and acrylamide (AM) onto carboxymethyl konjac glucomannan (CMKGM), and doped with montmorillonite (MMT), exhibited excellent thermal stability, a porous inner structure, large specific surface area (1.407 m/g), and high swelling capacity (107.3 g/g). The hydrogel achieved a maximum adsorption capacity of 694.1 mg/g and a removal rate of 99.5 %. The Langmuir isotherm and pseudo-second-order kinetic model best described the adsorption process. Regeneration and reuse tests confirmed that the hydrogel has excellent recyclability. In conclusion, the CAM4-MMT composite hydrogel efficiently removed basic fuchsin from water solutions, offering a new scheme for eliminating basic fuchsin using natural polysaccharides with promising applications.

摘要

本研究开发了一种纳米复合水凝胶 CAM4-MMT,用于高效去除水中的碱性品红染料。该水凝胶通过将丙烯酸(AA)和丙烯酰胺(AM)的共聚物接枝到羧甲基魔芋葡甘聚糖(CMKGM)上,并掺杂蒙脱土(MMT)制备而成,表现出优异的热稳定性、多孔的内部结构、较大的比表面积(1.407 m/g)和高的溶胀能力(107.3 g/g)。水凝胶的最大吸附容量为 694.1 mg/g,去除率为 99.5%。Langmuir 等温线和拟二级动力学模型较好地描述了吸附过程。再生和重复使用测试证实了水凝胶具有优异的可回收性。总之,CAM4-MMT 复合水凝胶可有效地从水溶液中去除碱性品红,为利用天然多糖去除碱性品红提供了一种新的方案,具有广阔的应用前景。

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