Experimental and Modeling Analysis of Mechanical Response of Composite Electrodes in Lithium Batteries.

The mechanical response is one of the main factors that influence the capacity and number of cycles of lithium batteries, which hinder its wide application. Therefore, it is crucial to perform an in-depth investigation of the electro-chemo-mechanical coupling performance and work mechanism of battery electrodes during the electrochemical reaction process. Usually, graphite is the main active material used in commercially used batteries, while silicon is gaining worldwide attention because of its large energy density. Here, graphite and silicon composite electrodes were prepared to obtain the electro-chemo-mechanical response during electrochemical cycling by an in situ bending deformation measurement. The findings indicate that the composite electrodes could induce a large bending deformation, with an increase in the state of charge (C-rate). And, with an increase in the C-rate, the deformation degree of the silicon composite electrode increases, while that of the graphite composite electrode decreases due to the hardening properties of the graphite particles. In addition, increasing the thickness ratio could induce an increase in the peak stress for both composite electrodes. This work gives a detailed analysis of the mechanical properties of composite electrodes and finds the working mechanism of the C-rate and thickness ratio, which can supply suggestions for the development of high-performance batteries.