School of Microelectronics, Tianjin University, Tianjin, 300072, China.
School of Electrical and Information Engineering, Tianjin University, Tianjin, 300072, China.
Talanta. 2024 Nov 1;279:126601. doi: 10.1016/j.talanta.2024.126601. Epub 2024 Jul 22.
Single gas quantification and mixed gas identification have been the major challenges in the field of gas detection. To address the shortcomings of chemo-resistive gas sensors, sensor arrays have been the subject of recent research. In this work, the research focused on both optimization of gas-sensing materials and further analysis of pattern recognition algorithms. Four bimetallic oxide-based gas sensors capable of operating at room temperature were first developed by introducing different modulating techniques on the sensing layer, including constructing surface oxygen defects, polymerizing conducting polymers, modifying Nano-metal, and compositing flexible substrates. The signals derived from the gas sensor array were then processed to eliminate noise and reduce dimension with the feature engineering. The gases of were qualitatively identified by support vector machine (SVM) model with an accuracy of 98.86 %. Meanwhile, a combined model of convolutional neural network and long short-term memory network (CNN-LSTM) was established to remove the interference samples and quantitatively estimate the concentration of the target gases. The combined model based on deep learning, which avoids the overfitting with local optimal solutions, effectively boosts the performance of concentration recognition with the lowest root mean square error (RMSE) of 2.3. Finally, a low-power artificial olfactory system was established by merging the multi-sensor data and applied for real-time and accurate judgment of the food freshness.
单一气体定量检测和混合气体识别一直是气体检测领域的主要挑战。为了解决化学电阻式气体传感器的缺点,传感器阵列成为了近期研究的主题。在这项工作中,研究重点既包括对气体传感材料的优化,也包括对模式识别算法的进一步分析。本工作首先通过在传感层引入不同的调制技术,开发了四种基于双金属氧化物的室温工作气体传感器,包括构建表面氧缺陷、聚合导电聚合物、修饰纳米金属和复合柔性基底。然后,通过特征工程处理来自气体传感器阵列的信号,以消除噪声并降低维度。使用支持向量机(SVM)模型对气体进行定性识别,准确率为 98.86%。同时,建立了卷积神经网络和长短期记忆网络(CNN-LSTM)的组合模型,以去除干扰样本并定量估计目标气体的浓度。基于深度学习的组合模型避免了局部最优解的过拟合,有效地提高了浓度识别的性能,最低均方根误差(RMSE)为 2.3。最后,通过合并多传感器数据建立了低功耗人工嗅觉系统,并应用于实时准确判断食物新鲜度。