压力诱导的单晶到单晶亚硝酸盐配体异构化并伴有压致变色效应。
Pressure-induced single-crystal-to-single-crystal nitrite ligand isomerisation accompanied by a piezochromic effect.
作者信息
Potempa Kinga, Paliwoda Damian, Jarzembska Katarzyna N, Kamiński Radosław, Krówczyński Adam, Borowski Patryk, Hanfland Michael
机构信息
Department of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, Poland.
European Spallation Source ERIC, Partikelgatan 2, 224 84 Lund, Sweden.
出版信息
Chem Commun (Camb). 2024 Aug 22;60(69):9194-9197. doi: 10.1039/d4cc02898h.
High-pressure structural study of a piezochromic crystal of a rare di--nitrito nickel(II) complex supported by computational analysis is presented. The examined system is not photoswitchable, however, in the 0-6.2 GPa pressure range the crystal undergoes two phase-transitions accompanied by a colour change and the nitrite ligand isomerisation, which is unique.
本文介绍了一种由计算分析支持的罕见二亚硝酸根镍（II）配合物的压致变色晶体的高压结构研究。所研究的体系不可光开关，然而，在0 - 6.2吉帕的压力范围内，该晶体经历了两次相变，伴随着颜色变化和亚硝酸根配体异构化，这是独一无二的。
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