Adaptive healing of stress-induced dynamic cracks in a metal-organic framework membrane using nanoparticles.

Dewatering of aqueous azeotropes is crucial and pervasive in raw chemical refineries and solvent recovery in the chemical industry but is recognized as one of the most energy-intensive processes. Pervaporation using crystalline molecular sieve membranes provides an energy-efficient solution, but stress loads stemming from thermal and mechanical risks of pervaporation are most likely to cause membrane cracks, which greatly reduces reliability of membranes in real-world applications. Here, we propose adaptive healing of stress-induced dynamic cracks (AHSDC) in the membrane in a risk-responding manner before separation by using in situ-formed nanoparticles in the same chemical environment. These nanoparticles naturally filled in fissure gaps once cracks formed in the membrane, forming adaptive healing zones. Without loss of dewatering capacity, the separation durability of the membrane after AHSDC was improved by at least two orders of magnitude. The membrane also exhibited tolerance to industrial-grade azeotropes that epitomize industrial multisource nature and complexity.