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提高金属有机框架材料的稳定性:方法与应用

Improving MOF stability: approaches and applications.

作者信息

Ding Meili, Cai Xuechao, Jiang Hai-Long

机构信息

Hefei National Laboratory for Physical Sciences at the Microscale , CAS Key Laboratory of Soft Matter Chemistry , Collaborative Innovation Center of Suzhou Nano Science and Technology , Department of Chemistry , University of Science and Technology of China , Hefei , Anhui 230026 , P. R. China . Email:

College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.

出版信息

Chem Sci. 2019 Oct 2;10(44):10209-10230. doi: 10.1039/c9sc03916c. eCollection 2019 Nov 28.

Abstract

Metal-organic frameworks (MOFs) have been recognized as one of the most important classes of porous materials due to their unique attributes and chemical versatility. Unfortunately, some MOFs suffer from the drawback of relatively poor stability, which would limit their practical applications. In the recent past, great efforts have been invested in developing strategies to improve the stability of MOFs. In general, stable MOFs possess potential toward a broader range of applications. In this review, we summarize recent advances in the design and synthesis of stable MOFs and MOF-based materials synthesis and/or post-synthetic structural processing. Also, the relationships between the stability and functional applications of MOFs are highlighted, and finally, the subsisting challenges and the directions that future research in this field may take have been indicated.

摘要

金属有机框架材料(MOFs)因其独特的性质和化学多功能性,已被公认为最重要的多孔材料类别之一。不幸的是,一些MOFs存在稳定性相对较差的缺点,这将限制它们的实际应用。最近,人们投入了大量精力来开发提高MOFs稳定性的策略。一般来说,稳定的MOFs具有更广泛的应用潜力。在这篇综述中,我们总结了稳定MOFs及基于MOF的材料在设计与合成、合成和/或合成后结构处理方面的最新进展。此外,还强调了MOFs稳定性与功能应用之间的关系,最后指出了该领域现存的挑战以及未来研究可能的方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b227/7069376/601e62fb6c25/c9sc03916c-s1.jpg

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