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快速启动和稳定运行中试规模反硝化-部分亚硝化/厌氧氨氧化工艺处理电镀废水。

Rapid start-up and stable operation of pilot scale denitrification-partial nitritation/anammox process for treating electroplating tail wastewater.

机构信息

School of Environment and Energy, South China University of Technology, Guangzhou 510006, China; The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, 510006, China.

School of Environment, South China Normal University, Guangzhou 510006, China; Hua An Biotech Co., Ltd., Foshan 528300, China.

出版信息

Bioresour Technol. 2024 Oct;409:131192. doi: 10.1016/j.biortech.2024.131192. Epub 2024 Jul 31.

Abstract

This study explored a novel economical and efficient process for treating actual low-ammonia nitrogen electroplating tail wastewater. A pilot scale system of denitrification-partial nitrification/anaerobic ammonium oxidation (DN-PN/A) was constructed and operated for 190 days. The partial nitrification (PN) reactor, filled with zeolite, increased free ammonia concentration beyond the nitrite oxidizing bacteria threshold and successfully supplied NO-N, with nitrite accumulation rate exceeding 90 %. Over 109 days, the total nitrogen removal rate achieved was 80.2 ± 7.41 %, and the chemical oxygen demand removal rate reached 79.68 ± 9.53 %. The dominant functional bacteria were Nitrosomonas (5.45 %) and Candidatus Anammoxoglobus (28.84 %) in PN reactor and anaerobic ammonium oxidation (Anammox) reactor. This process, characterized by rapid start-up, strong shock resistance, and low cost, alleviates the pressure of ammonium pollution control, promotes the sustainable development of the electroplating industry and has the potential for application in the treatment of other industrial wastewater.

摘要

本研究探索了一种新颖的经济高效处理实际低氨氮电镀尾水的方法。构建并运行了一个中试规模的反硝化-部分硝化/厌氧氨氧化(DN-PN/A)系统,运行了 190 天。沸石填充的部分硝化(PN)反应器提高了游离氨浓度,超过了亚硝酸盐氧化菌的阈值,并成功提供了 NO-N,亚硝酸盐积累率超过 90%。在 109 天的时间里,总氮去除率达到 80.2±7.41%,化学需氧量去除率达到 79.68±9.53%。PN 反应器和厌氧氨氧化(Anammox)反应器中的优势功能菌为亚硝化单胞菌(5.45%)和疑似厌氧氨氧化菌(28.84%)。该工艺具有启动迅速、抗冲击能力强、成本低等特点,缓解了铵污染控制的压力,促进了电镀行业的可持续发展,具有在处理其他工业废水方面的应用潜力。

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