TiCT/CdZnS composites constructed of Schottky heterojunction for efficient photocatalytic reduction of U(VI).

Photocatalysis has emerged as a extremely promising green technology for the treatment of uranium-containing wastewater. This study focuses on the fabrication of TiCT/CdZnS composites with Schottky junctions through the in-situ growth of CdZnS on TiCT nanosheets, enabling efficient photoreduction of U(VI) without the requirement of sacrificial agents. The results demonstrate that the TiCT/CdZnS composites achieve remarkable 99.48 % U(VI) reduction efficiency within 60 min in a 100 ppm uranium solution. Furthermore, the removal rate remains above 90 % after five cycles. The formation of Schottky heterojunctions by TiCT and CdZnS leads to the generation of an internal electric field that significantly promotes the rapid separation and transfer of photogenerated carriers, thereby enhancing the photocatalytic reduction efficiency of TiCT/CdZnS-3:100 (TC/CZS-3:100). A considerable amount of electrons accumulate on TiCT via the Schottky barrier, effectively facilitating the reduction of U(VI) to U(IV). As a co-catalyst, TiCT enhances the photocatalytic performance and stability of CdZnS. Moreover, the practical application in the waste liquid of rare earth tailings reveals that the removal rate can be as high as 91.24 %. This research is of significant value in the development of effective photocatalysts for the elimination of uranium from wastewater.