Chen Xueshuai, Wang Huili, Zhou Tongxin, Han Qian
Biological Engineering Technology Innovation Center of Shandong Province, Heze Branch, Qilu University of Technology (Shandong Academy of Sciences), Heze 274000, China.
State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China.
Langmuir. 2024 Aug 20;40(33):17510-17516. doi: 10.1021/acs.langmuir.4c01697. Epub 2024 Aug 6.
Based on the interaction of polyaluminum chloride (PAC) and chitosan (CTS) at the molecular level, an organic/inorganic composite material was designed for the preparation of alkyl ketene dimer (AKD) emulsion. This paper aimed to explore the influence of PAC/CTS on the physicochemical properties, microstructure, and sizing efficiency of AKD emulsions. The PAC/CTS complex forms a denser adsorption layer at the oil-water interface at the microscopic level. With the increase in CTS concentration, the AKD emulsions displayed excellent stability after high-speed centrifugation. In addition, the addition of CTS can effectively improve the sizing efficiency of the emulsion. Therefore, this study proposed a strategy of PAC/CTS as an emulsifier, and the related interaction mechanism was explored, which further expands the application of inorganic/organic composites in the field of colloidal chemistry.
基于聚合氯化铝（PAC）与壳聚糖（CTS）在分子水平上的相互作用，设计了一种用于制备烷基烯酮二聚体（AKD）乳液的有机/无机复合材料。本文旨在探究PAC/CTS对AKD乳液的物理化学性质、微观结构及施胶效率的影响。PAC/CTS复合物在微观层面的油水界面形成了更致密的吸附层。随着CTS浓度的增加，AKD乳液在高速离心后表现出优异的稳定性。此外，CTS的添加可有效提高乳液的施胶效率。因此，本研究提出了以PAC/CTS作为乳化剂的策略，并探究了相关的相互作用机制，进一步拓展了无机/有机复合材料在胶体化学领域的应用。
