High-Performance Yet Sustainable Triboelectric Nanogenerator Based on Sulfur-Rich Polymer Composite with MXene Segregated Structure.

State-of-the-art triboelectric nanogenerators (TENGs) typically employ fluoropolymers, highly negative chargeable materials in triboelectric series. However, many researchers nowadays are concerned about environmental pollution caused by poly-and per-fluoroalkyl substances (PFAS) due to their critical immunotoxicity as fluoropolymers are likely to release PFAS into the ecosystem during their life cycle. Herein, a sulfur-rich polymer (SRP)/MXene composite, offering high-performance yet sustainable TENG is developed. Value-addition of sulfur into SRP-based TENG has huge advantages since sulfur is abundant waste from petroleum refining and possesses the highest electron affinity (-200 kJ mol) among polymerizable atoms. MXene segregated structure is introduced into SRP to achieve homogeneous distribution without electrical percolation by utilizing below 0.5 wt% of MXene, resulting in a significantly enhanced dielectric constant without a drastic increase of dielectric loss. Due to homogeneous MXene distribution, SRP/MXene composite-based TENG demonstrates 2.9 times and 19.5 times enhances peak voltage and peak current compared to previous SRP-based TENGs. Additionally, it exhibits reusability without critical reduction of modulus and TENG performance due to dynamically exchangeable disulfide bonds. Finally, after the corona discharging and scaling-up process to a 4-inch wafer size, SRP/MXene composite-based TENG exhibits an 8.4 times improvement in peak power density, reaching 3.80 W m compared to previous SRP-based TENGs.