基于氮杂环卡宾的双子两亲分子表现出独特的自组装行为——烷基连接链长度的奇偶效应。
Azaylide-based gemini amphiphiles displaying unique self-assembling behavior an even-odd effect of alkyl linker chain length.
作者信息
Akiyama Yoshimori, Yamashina Masahiro, Toyota Shinji
机构信息
Department of Chemistry, School of Science, Tokyo Institute of Technology, Meguro-ku, 2-12-1 Ookayama, Tokyo 152-8551, Japan.
出版信息
Soft Matter. 2024 Aug 22;20(33):6539-6543. doi: 10.1039/d4sm00789a.
PMID:39108245
Abstract
Herein, we report a straightforward synthesis of azaylide-based gemini amphiphiles using bis(diphenylphosphino)alkanes the Staudinger reaction. The prepared gemini amphiphiles exhibited an even-odd effect in their self-assembly behavior depending on the length of the alkyl linkers. Furthermore, the assembled micelles had high host capability toward hydrophobic guests in water.
摘要
在此，我们报道了一种使用双（二苯基膦基）烷烃通过施陶丁格反应直接合成氮杂叶立德基双子两亲分子的方法。所制备的双子两亲分子在其自组装行为中表现出取决于烷基连接链长度的奇偶效应。此外，组装的胶束在水中对疏水性客体具有高容纳能力。
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