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在PVA/HPO基质中用木质素增强碳纤维对柔性超级电容器的电化学性能。

Enhancing electrochemical performance of carbon fiber with lignin for flexible supercapacitors in PVA/HPO matrix.

作者信息

Muñoz Bianca K, Serroukh Ilias, Sánchez María, Ureña Alejandro

机构信息

Material Science and Engineering Area, Universidad Rey Juan Carlos, ESCET, C/Tulipán s/n. Móstoles, 28933 Madrid, Spain.

出版信息

iScience. 2024 Jul 2;27(8):110433. doi: 10.1016/j.isci.2024.110433. eCollection 2024 Aug 16.

DOI:10.1016/j.isci.2024.110433
PMID:39108739
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11301100/
Abstract

Lignin is an unlimited resource of an aromatic natural polymer useful for multiple applications, though its use remains limited due to the lack of technology developments. The introduction of lignin as coating of fibers and textile for composites is being recently studied with very promising results. Here, commercial woven carbon fibers (WCFs) have been superficially modified following an easy approach to introduce lignin and carbonize it to enhance the electrochemical performance of the fibers. The modified carbon fibers containing lignin were tested as electrodes using KCl 3 M as electrolyte, reaching 5 F/g at 10 mVs. A symmetric supercapacitor was fabricated using these electrodes, and a proof of concept based on a red and yellow light-emitting diode (LED) powered on and a bending test were done. The supercapacitor was able to recover 99% of its capacitance when returned to its original unbent position.

摘要

木质素是一种可用于多种应用的芳香族天然聚合物的无限资源,尽管由于技术发展的缺乏,其使用仍然有限。最近,人们正在研究将木质素作为复合材料的纤维和纺织品涂层,取得了非常有前景的成果。在这里,商业编织碳纤维(WCFs)已经通过一种简单的方法进行了表面改性,以引入木质素并将其碳化,从而提高纤维的电化学性能。以含木质素的改性碳纤维作为电极,使用3M KCl作为电解质进行测试,在10mV时达到5F/g。使用这些电极制作了一个对称超级电容器,并基于点亮红色和黄色发光二极管(LED)进行了概念验证和弯曲测试。当超级电容器恢复到原始未弯曲位置时,其电容能够恢复99%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/e3611738aab9/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/d7aab338f523/fx1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/6fec9351b05a/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/bb695056feae/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/52f258c0739f/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/7c485864b88e/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/c0a2a8ba0803/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/0d7d08125c32/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/e3611738aab9/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/d7aab338f523/fx1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/3a81b44c1fcc/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/6fec9351b05a/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/bb695056feae/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/52f258c0739f/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/7c485864b88e/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/c0a2a8ba0803/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/0d7d08125c32/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7f26/11301100/e3611738aab9/gr8.jpg

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本文引用的文献

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Investigation of the Protective Function of a Lignin Coating of Natural Fiber Geotextiles against Biodegradation.天然纤维土工布木质素涂层对生物降解的保护作用研究
Materials (Basel). 2023 Jul 6;16(13):4849. doi: 10.3390/ma16134849.
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Sustainable Lignin-Derived Hierarchical Porous Carbon for Supercapacitors: A Novel Approach for Holding Electrochemical Attraction Natural Texture Property of Precursor.
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Three-dimensional hierarchical porous lignin-derived carbon/WO for high-performance solid-state planar micro-supercapacitor.三维分级多孔木质素衍生碳/WO 用于高性能固态平面微超级电容器。
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