Echeverría Jorge, Alvarez Santiago
Instituto de Síntesis Química y Catalisis Homogénea (ISQCH) and Departmento de Química Inorgánica, Facultad de Ciencias, Universidad de Zaragoza Pedro Cerbuna 12 50009 Zaragoza Spain
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, and Institut de Química Teòrica i Computacional, Universitat de Barcelona Martí i Franquès 1-11 08028 Barcelona Spain
Chem Sci. 2024 Jul 15;15(31):12166-12168. doi: 10.1039/d4sc03827d. eCollection 2024 Aug 7.
The recent proposal of the van der Waals crust as the spherical section comprised between the atomic radius and the van der Waals radius of an element generated a commentary by Grochala pointing out some supposed weaknesses of the approach (https://doi.org/10.1039/D3SC90191B). Our inital study is complemented herein by an analysis of the effects of the different size of the two interacting crusts, which shows that the penetration index defined earlier can adequately handle the misfit crust interactions.
最近提出的范德华壳层是指元素的原子半径和范德华半径之间的球形截面，这引发了格罗查拉的一篇评论，指出了该方法的一些所谓弱点（https://doi.org/10.1039/D3SC90191B）。本文通过分析两个相互作用壳层不同尺寸的影响对我们最初的研究进行了补充，结果表明，先前定义的穿透指数能够充分处理不匹配壳层的相互作用。
