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高压P2-NaTMO材料的最新进展及其未来展望。

Recent progress in high-voltage P2-Na TMO materials and their future perspectives.

作者信息

Li Manni, Lin Weiqi, Ji Yurong, Guan Lianyu, Qiu Linyuan, Chen Yuhong, Lu Qiaoyu, Ding Xiang

机构信息

College of Chemistry and Materials Science, Fujian Normal University Fuzhou 350007 China

Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University Fuzhou 350108 China.

出版信息

RSC Adv. 2024 Aug 8;14(34):24797-24814. doi: 10.1039/d4ra04790g. eCollection 2024 Aug 5.

DOI:10.1039/d4ra04790g
PMID:39119284
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11306967/
Abstract

P2-type layered materials (Na TMO) have become attractive cathode electrodes owing to their high theoretical energy density and simple preparation. However, they still face severe phase transition and low conductivity. Current research on Na TMO is mostly focused on the modification of bulk materials, and the application performances have been infrequently addressed. This review summarizes the information on current common P2-Na TMO materials and discusses their sodium-storage mechanisms. Furthermore, modification strategies to improve their performance are addressed for practical applications based on a range of key parameters (output voltage, specific capacity, and lifespan). We also discuss the future development trends and application prospects for P2 cathode materials.

摘要

P2型层状材料（Na TMO）因其高理论能量密度和简单的制备方法而成为有吸引力的阴极电极。然而，它们仍然面临严重的相变和低导电性问题。目前对Na TMO的研究大多集中在块状材料的改性上，而很少涉及应用性能。本文综述了当前常见的P2-Na TMO材料的信息，并讨论了它们的储钠机制。此外，基于一系列关键参数（输出电压、比容量和寿命），针对实际应用提出了提高其性能的改性策略。我们还讨论了P2阴极材料的未来发展趋势和应用前景。

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