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Ratiometric fluorescence probe based on carbon dots and p-phenylenediamine-derived nanoparticles for the sensitive detection of manganese ions.

作者信息

Hu Anqi, Chen Guoqing, Huang Anlan, Li Lei, Ma Chaoqun, Yang Taiqun, Gao Hui, Gu Jiao, Zhu Chun, Shang Yunpeng, Wu Yamin

机构信息

School of Science, Jiangnan University, Wuxi, 214122, China.

Jiangsu Provincial Research Center of Light Industrial Optoelectronic Engineering and Technology, Wuxi, 214122, China.

出版信息

Mikrochim Acta. 2024 Aug 10;191(9):529. doi: 10.1007/s00604-024-06612-w.


DOI:10.1007/s00604-024-06612-w
PMID:39123066
Abstract

A ratiometric fluorescence probe based on carbon quantum dots with 420 nm emission (bCQDs) and a p-phenylenediamine-derived fluorescence probe with 550 nm emission (yprobe) is constructed for the detection of Mn. The presence of Mn results in the enhanced absorption band at 400 nm of yprobe, and the fluorescence of yprobe is significantly enhanced based on the chelation-enhanced fluorescence mechanism. The fluorescence of bCQDs is then quenched based on the inner filtration effect. The ratio (I/I) linearly increases with the increase of Mn concentration within 2.00 × 10-1.50 × 10 M, and the limit of detection is 1.76 × 10 M. Given the fluorescence color changing from blue to yellow, the visual sensing of Mn is feasible based on bCQDs/yprobe coupled with RGB value analysis. The practicability of the proposed method has been verified in tap water, lake water, and sparkling water beverage, indicating that bCQDs/yprobe has promising application in Mn monitoring.

摘要

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本文引用的文献

[1]
A feasibility study on production, characterisation and application of empty fruit bunch oil palm biochar for Mn removal from aqueous solution.

Environ Pollut. 2023-2-1

[2]
Improving Minutiae Image of Latent Fingerprint Detection on Non-Porous Surface Materials under UV Light Using Sulfur Doped Carbon Quantum Dots from Magnolia Grandiflora Flower.

Nanomaterials (Basel). 2022-9-21

[3]
Use of curcumin-modified diamond nanoparticles in cellular imaging and the distinct ratiometric detection of Mg/Mn ions.

Nanoscale Adv. 2021-6-23

[4]
Dual modes of fluorescence sensing and smartphone readout for sensitive and visual detection of mercury ions in Porphyra.

Anal Chim Acta. 2022-9-15

[5]
One-Step and One-Precursor Hydrothermal Synthesis of Carbon Dots with Superior Antibacterial Activity.

ACS Appl Bio Mater. 2020-10-19

[6]
Nitrogen and sulfur co-doped carbon dots with bright fluorescence for intracellular detection of iron ion and thiol.

J Colloid Interface Sci. 2022-4

[7]
The facile synthesis of nitrogen and sulfur co-doped carbon dots for developing a powerful "on-off-on" fluorescence probe to detect glutathione in vegetables.

Food Chem. 2022-3-15

[8]
Utilization of waste biomass of Poa pratensis for green synthesis of n-doped carbon dots and its application in detection of Mn and Fe.

Chemosphere. 2022-1

[9]
Carboxymethyl chitosan crosslinked ꞵ-cyclodextrin containing hydrogen bonded NC QDs nanocomposites to design fluorescence probes for manganese ion (II) sensing.

Mater Sci Eng C Mater Biol Appl. 2021-2

[10]
Iron and manganese removal: Recent advances in modelling treatment efficiency by rapid sand filtration.

Water Res. 2016-11-9

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