Wang Danyang, Yu Dongqi, Xu Menghan, Chen Xue, Gu Jilin, Huang Lei
School of Physics and Electronic Technology, Liaoning Normal University, Dalian 116029, China.
Research Center of Nano Science and Technology, College of Sciences, Shanghai University, Shanghai 200444, China.
Sensors (Basel). 2024 Jul 26;24(15):4866. doi: 10.3390/s24154866.
Ethanol sensors have found extensive applications across various industries, including the chemical, environmental, transportation, and healthcare sectors. With increasing demands for enhanced performance and reduced energy consumption, there is a growing need for developing new ethanol sensors. Micro-electromechanical system (MEMS) devices offer promising prospects in gas sensor applications due to their compact size, low power requirements, and seamless integration capabilities. In this study, SnO-TiO nanocomposites with varying molar ratios of SnO and TiO were synthesized via ball milling and then printed on MEMS chips for ethanol sensing using electrohydrodynamic (EHD) printing. The study indicates that the two metal oxides dispersed evenly, resulting in a well-formed gas-sensitive film. The SnO-TiO composite exhibits the best performance at a molar ratio of 1:1, with a response value of 25.6 to 50 ppm ethanol at 288 °C. This value is 7.2 times and 1.8 times higher than that of single SnO and TiO gas sensors, respectively. The enhanced gas sensitivity can be attributed to the increased surface reactive oxygen species and optimized material resistance resulting from the chemical and electronic effects of the composite.
乙醇传感器已在包括化工、环境、交通和医疗保健等各个行业中得到广泛应用。随着对提高性能和降低能耗的需求不断增加,开发新型乙醇传感器的需求也日益增长。微机电系统(MEMS)器件因其尺寸紧凑、功耗低和集成能力强等特点,在气体传感器应用中展现出广阔前景。在本研究中,通过球磨合成了具有不同摩尔比的SnO和TiO的SnO-TiO纳米复合材料,然后使用电液动力(EHD)打印技术将其印刷在MEMS芯片上用于乙醇传感。研究表明,两种金属氧化物均匀分散,形成了良好的气敏薄膜。SnO-TiO复合材料在摩尔比为1:1时表现出最佳性能,在288°C下对50 ppm乙醇的响应值为25.6。该值分别比单一SnO和TiO气体传感器高出7.2倍和1.8倍。气敏性增强可归因于复合材料的化学和电子效应导致的表面活性氧物种增加和材料电阻优化。