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基于CsPbCl纳米晶体的用于人工伤害感受器的柔性忆阻器。

A Flexible Memristor Based on CsPbCl Nanocrystals for an Artificial Nociceptor.

作者信息

Chen Ting, Ran Qian, Wang Yuchan, Zhang Wenxia, Tang Xiaosheng, Han Yemei, Zhang Kailiang

机构信息

Tianjin Key Laboratory of Film Electronic and Communication Devices, School of Integrated Circuit Science and Engineering, Tianjin University of Technology, Tianjin 300384, China.

Optoelectronic Engineering, Chongqing University of Posts and Telecommunications, Chongqing 400065, China.

出版信息

J Phys Chem Lett. 2024 Aug 22;15(33):8555-8561. doi: 10.1021/acs.jpclett.4c01944. Epub 2024 Aug 13.

Abstract

Halide perovskites (HPs) based memristors show great potential in the simulation of biological neurons. Herein, a memristor with Ag/PMMA&CsPbCl/ITO structure is developed by incorporating CsPbCl nanocrystals (NCs) into poly(methyl methacrylate) (PMMA) as the functional layer. The device exhibits typical bipolar resistive behavior, low operating voltage, good endurance of more than 400 cycles, consistent and excellent ON/OFF ratio (≈ 10), and high mechanical bending stability (bending times = 1000). The RS mechanism has been well explained by the electric field induced formation and rupture of Ag filaments in the PMMA&CsPbCl layer. More importantly, the memristor successfully displays fundamental nociceptive functions including threshold, nonadaptation, relaxation, and sensitization (allodynia and hyperalgesia). To demonstrate the feasibility of the artificial nociceptor, a pressure nociceptor system is constructed using the Ag/PMMA&CsPbCl/ITO device. These results provide new perspectives for the development of next-generation, high-performance HPs based neural morphology devices.

摘要

基于卤化物钙钛矿(HPs)的忆阻器在模拟生物神经元方面显示出巨大潜力。在此,通过将CsPbCl纳米晶体(NCs)掺入聚甲基丙烯酸甲酯(PMMA)作为功能层,开发了一种具有Ag/PMMA&CsPbCl/ITO结构的忆阻器。该器件表现出典型的双极电阻行为、低工作电压、超过400次循环的良好耐久性、一致且优异的开/关比(≈10)以及高机械弯曲稳定性(弯曲次数 = 1000)。通过电场诱导PMMA&CsPbCl层中Ag细丝的形成和断裂,很好地解释了电阻开关(RS)机制。更重要的是,该忆阻器成功展示了基本的伤害感受功能,包括阈值、非适应性、弛豫和敏化(异常性疼痛和痛觉过敏)。为了证明人工伤害感受器的可行性,使用Ag/PMMA&CsPbCl/ITO器件构建了一个压力伤害感受器系统。这些结果为下一代基于高性能HPs的神经形态器件的开发提供了新的视角。

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