Zhou Xinyi, Ma Weigang, Gao Huayun, Wang Chuanmin, Samarth Chanatip, Kongparakul Suwadee, Tran Nguyen-Minh-An, Wang Junfeng, Liu Xiaotao, Tan Hua, Zhang Haibo
School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, China.
Department of Chemistry, Faculty of Science and Technology, Thammasat University, Pathumthani 12140, Thailand.
Ultrasonics. 2024 Sep;143:107429. doi: 10.1016/j.ultras.2024.107429. Epub 2024 Aug 8.
Piezoelectric composite ceramics, as the key components of ultrasonic transducers, have their vibration modes, electromechanical coupling performance, and acoustic impedance closely related to the volume fraction of ceramics. This study employed a novel digital light processing 3D printing technique (DLP) to fabricate 0.5Ba(ZrTi)O-0.5(BaCa)TiO (BCZT)-based 1-3 piezoelectric composite ceramics with different ceramic volume fractions (15.6 %, 23.5 %, 36.2 %, 48.4 %, 59.5 %). It demonstrates the suitability of the DLP process for the fabrication of 1-3 piezoelectric composite ceramics and investigates the influence of ceramic volume fraction on the performance of these ceramics. When the piezoelectric ceramic volume fraction was 59.5 %, the piezoelectric coefficient effective d of the 1-3 piezoelectric composite device reached 315 pC/N, demonstrating excellent piezoelectric performance. The acoustic impedance Z was 16.3 MRayl, and the thickness electromechanical coupling coefficient k was 0.55, indicating high energy conversion efficiency. The air-coupled ultrasonic transducer prepared from the 1-3 piezoelectric composite ceramics with a ceramic volume fraction of 59.5 % exhibited a round-trip insertion loss (IL) of -70.32 dB and a -6 dB bandwidth (BW) of 7.42 %. This work provides a more convenient and new method for the preparation of lead-free piezoelectric ceramic ultrasonic transducers.
压电复合陶瓷作为超声换能器的关键部件,其振动模式、机电耦合性能和声阻抗与陶瓷的体积分数密切相关。本研究采用一种新型数字光处理3D打印技术(DLP)制备了具有不同陶瓷体积分数(15.6%、23.5%、36.2%、48.4%、59.5%)的0.5Ba(ZrTi)O-0.5(BaCa)TiO(BCZT)基1-3型压电复合陶瓷。它证明了DLP工艺适用于制备1-3型压电复合陶瓷,并研究了陶瓷体积分数对这些陶瓷性能的影响。当压电陶瓷体积分数为59.5%时,1-3型压电复合器件的有效压电系数d达到315 pC/N,展现出优异的压电性能。声阻抗Z为16.3 MRayl,厚度机电耦合系数k为0.55,表明能量转换效率高。由陶瓷体积分数为59.5%的1-3型压电复合陶瓷制备的空气耦合超声换能器的往返插入损耗(IL)为-70.32 dB,-6 dB带宽(BW)为7.42%。这项工作为制备无铅压电陶瓷超声换能器提供了一种更便捷的新方法。