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Soft colloidal monolayers with reflection symmetry through confined drying.

作者信息

Majumder Sanjib, Basavaraj Madivala G, Satapathy Dillip K

机构信息

Soft Material Laboratory, Department of Physics, IIT Madras Chennai-600036 India.

Centre for Soft and Biological Matter, IIT Madras Chennai-600036 India

出版信息

Nanoscale Adv. 2024 Jul 23;6(19):4907-21. doi: 10.1039/d4na00542b.


DOI:10.1039/d4na00542b
PMID:39139712
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11317906/
Abstract

Colloidal monolayers serve as fundamental building blocks in fabricating diverse functional materials, pivotal for surface modifications, chemical reactivity, and controlled assembly of nanoparticles. In this article, we report the formation of colloidal monolayers generated by drying an aqueous droplet containing soft colloids confined between two hydrophilic parallel plates. The analysis of the kinetics of evaporation in this confined mode showed that: (i) for a significant portion of the drying time, the drops adopt a catenoid configuration; (ii) in the penultimate stage of drying, the catenoid structure undergoes division into two daughter droplets; (iii) the three-phase contact line remains pinned at a specific location while it continuously slips at all other locations. The interplay between interface-assisted particle deposition onto the solid substrate and the time evolution of particle concentration within the droplet during evaporation results in unique microstructural features in the deposited patterns. Notably, these deposit patterns exhibit reflection symmetry. The microstructural features of the dried deposits are further quantified by calculating the particle number density, inter-particle separation, areal disorder parameter, and bond orientational order parameter. The variation of these parameters for deposits formed under different conditions, such as by altering the spacing between parallel plates and the concentration of microgel particles in the droplet, is discussed.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/5f9ddb5e00c9/d4na00542b-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/a953e72ba828/d4na00542b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/947f74108fd4/d4na00542b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/b0f553747017/d4na00542b-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/11399a427904/d4na00542b-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/f13e6b05807c/d4na00542b-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/4d4ae3f1fa01/d4na00542b-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/d8d832972d08/d4na00542b-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/7f8d1475636a/d4na00542b-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/deb23f67bb76/d4na00542b-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/426488ce3d88/d4na00542b-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/512b496f6357/d4na00542b-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/5f9ddb5e00c9/d4na00542b-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/a953e72ba828/d4na00542b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/947f74108fd4/d4na00542b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/b0f553747017/d4na00542b-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/11399a427904/d4na00542b-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/f13e6b05807c/d4na00542b-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/4d4ae3f1fa01/d4na00542b-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/d8d832972d08/d4na00542b-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/7f8d1475636a/d4na00542b-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/deb23f67bb76/d4na00542b-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/426488ce3d88/d4na00542b-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/512b496f6357/d4na00542b-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2f8/11421558/5f9ddb5e00c9/d4na00542b-f12.jpg

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引用本文的文献

[1]
Confined colloidal droplets dry to form circular mazes.

Proc Natl Acad Sci U S A. 2025-8-12

本文引用的文献

[1]
Depletion zone in two-dimensional deposits of soft microgel particles.

J Colloid Interface Sci. 2023-7-15

[2]
Triple-line dynamics of a soft colloid-laden drop on a hydrophobic surface.

Soft Matter. 2023-3-1

[3]
Malleable Patterns from the Evaporation of a Colloidal Liquid Bridge: Coffee Ring to the Scallop Shell.

Langmuir. 2022-5-10

[4]
An Experimental Investigation of Evaporation of Ethanol-Water Droplets Laden with Alumina Nanoparticles on a Critically Inclined Heated Substrate.

Langmuir. 2022-4-19

[5]
Colloidal Deposits via Capillary Bridge Evaporation and Particle Sorting Thereof.

Langmuir. 2021-10-19

[6]
Controllable dried patterns of colloidal drops.

J Colloid Interface Sci. 2022-1-15

[7]
Evaporative self-assembly of soft colloidal monolayers: the role of particle softness.

Soft Matter. 2021-9-14

[8]
Colloidal monolayers with cell-like tessellations via interface assisted evaporative assembly.

J Colloid Interface Sci. 2021-2-1

[9]
Applying droplets and films in evaporative lithography.

Adv Colloid Interface Sci. 2020-9-17

[10]
Evaporation of Inclined Drops: Formation of Asymmetric Ring Patterns.

Langmuir. 2020-7-21

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